FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2548892766> ?p ?o ?g. }

• W2548892766 endingPage "12210" @default.
• W2548892766 startingPage "12193" @default.
• W2548892766 abstract "In spite of considerable research on the nature of aqueous alcohol mixtures that are characterized by microscopic inhomogeneity or incomplete mixing at the molecular level, transport properties have received little attention. We report the results of a study on diffusion in the ternary mixture of water with two alcohols, that is, water + methanol + ethanol, which is investigated on microscopic and macroscopic scales by means of molecular simulation and Taylor dispersion experiments. A novel protocol is developed for the comparison of mutual diffusion coefficients sampled by two fundamentally different approaches, which allows for their critical analysis. Because of complex intermolecular interactions, given by the presence of hydrogen bonding, the analysis of transport processes in this mixture is challenging for not only on the microscopic scale for simulation techniques but also on the macroscopic scale due to unfavorable optical properties. Binary limits of the Fick diffusion matrix are used for validation of the experimental ternary mixture results together with the verification of the validity of the phenomenological Onsager reciprocal relations. The Maxwell–Stefan diffusion coefficients and the thermodynamic factor are sampled by molecular simulation consistently on the basis of given force field models. The protocol for the comparison of the results from both approaches is also challenging because Fick diffusion coefficients of ternary mixtures depend on the frame of reference. Accordingly, the measured coefficients are transformed from the volume-averaged to the molar-averaged frame of reference, and it is demonstrated that both approaches provide not only similar qualitative behavior along two concentration paths but also strong quantitative agreement. This coordinated work using different approaches to study diffusion in multicomponent mixtures is expected to be a significant step forward for the accurate assessment of cross-diffusion." @default.
• W2548892766 created "2016-11-11" @default.
• W2548892766 creator A5003765539 @default.
• W2548892766 creator A5050997845 @default.
• W2548892766 creator A5055373823 @default.
• W2548892766 creator A5074676647 @default.
• W2548892766 creator A5082093150 @default.
• W2548892766 date "2016-11-21" @default.
• W2548892766 modified "2023-10-18" @default.
• W2548892766 title "Diffusion in Multicomponent Liquids: From Microscopic to Macroscopic Scales" @default.
• W2548892766 cites W1481169147 @default.
• W2548892766 cites W1786905458 @default.
• W2548892766 cites W1964878278 @default.
• W2548892766 cites W1965249226 @default.
• W2548892766 cites W1977991499 @default.
• W2548892766 cites W1979343792 @default.
• W2548892766 cites W1984271832 @default.
• W2548892766 cites W1987768718 @default.
• W2548892766 cites W1993365398 @default.
• W2548892766 cites W1993913798 @default.
• W2548892766 cites W1996114216 @default.
• W2548892766 cites W1997658654 @default.
• W2548892766 cites W2000456051 @default.
• W2548892766 cites W2003003096 @default.
• W2548892766 cites W2004020442 @default.
• W2548892766 cites W2006461837 @default.
• W2548892766 cites W2007960263 @default.
• W2548892766 cites W2009585311 @default.
• W2548892766 cites W2021195744 @default.
• W2548892766 cites W2021296496 @default.
• W2548892766 cites W2030159869 @default.
• W2548892766 cites W2034333249 @default.
• W2548892766 cites W2035405387 @default.
• W2548892766 cites W2038933472 @default.
• W2548892766 cites W2045264073 @default.
• W2548892766 cites W2049690072 @default.
• W2548892766 cites W2051335845 @default.
• W2548892766 cites W2056580897 @default.
• W2548892766 cites W2058693409 @default.
• W2548892766 cites W2063008187 @default.
• W2548892766 cites W2065131215 @default.
• W2548892766 cites W2065549856 @default.
• W2548892766 cites W2069233130 @default.
• W2548892766 cites W2078019542 @default.
• W2548892766 cites W2087917487 @default.
• W2548892766 cites W2090078947 @default.
• W2548892766 cites W2090143239 @default.
• W2548892766 cites W2090959398 @default.
• W2548892766 cites W2095363658 @default.
• W2548892766 cites W2103734924 @default.
• W2548892766 cites W2109469331 @default.
• W2548892766 cites W2118085411 @default.
• W2548892766 cites W2119421377 @default.
• W2548892766 cites W2122974066 @default.
• W2548892766 cites W2138068074 @default.
• W2548892766 cites W2148397624 @default.
• W2548892766 cites W2162082827 @default.
• W2548892766 cites W2234492351 @default.
• W2548892766 cites W2314384374 @default.
• W2548892766 cites W2321094000 @default.
• W2548892766 cites W2329549016 @default.
• W2548892766 cites W2331306280 @default.
• W2548892766 cites W3159383888 @default.
• W2548892766 cites W4240384253 @default.
• W2548892766 doi "https://doi.org/10.1021/acs.jpcb.6b09810" @default.
• W2548892766 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27933944" @default.
• W2548892766 hasPublicationYear "2016" @default.
• W2548892766 type Work @default.
• W2548892766 sameAs 2548892766 @default.
• W2548892766 citedByCount "25" @default.
• W2548892766 countsByYear W25488927662017 @default.
• W2548892766 countsByYear W25488927662018 @default.
• W2548892766 countsByYear W25488927662019 @default.
• W2548892766 countsByYear W25488927662020 @default.
• W2548892766 countsByYear W25488927662021 @default.
• W2548892766 countsByYear W25488927662023 @default.
• W2548892766 crossrefType "journal-article" @default.
• W2548892766 hasAuthorship W2548892766A5003765539 @default.
• W2548892766 hasAuthorship W2548892766A5050997845 @default.
• W2548892766 hasAuthorship W2548892766A5055373823 @default.
• W2548892766 hasAuthorship W2548892766A5074676647 @default.
• W2548892766 hasAuthorship W2548892766A5082093150 @default.
• W2548892766 hasConcept C120665830 @default.
• W2548892766 hasConcept C121332964 @default.
• W2548892766 hasConcept C121864883 @default.
• W2548892766 hasConcept C126530081 @default.
• W2548892766 hasConcept C138777275 @default.
• W2548892766 hasConcept C147597530 @default.
• W2548892766 hasConcept C153081606 @default.
• W2548892766 hasConcept C159467904 @default.
• W2548892766 hasConcept C162324750 @default.
• W2548892766 hasConcept C166950319 @default.
• W2548892766 hasConcept C176217482 @default.
• W2548892766 hasConcept C178790620 @default.
• W2548892766 hasConcept C185592680 @default.
• W2548892766 hasConcept C199360897 @default.
• W2548892766 hasConcept C21547014 @default.
• W2548892766 hasConcept C32909587 @default.

• next