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- W2549274613 abstract "A new route for the synthesis of 3-substituted and 8-hydroxy-3-substituted isocoumarins has been developed by using modified Julia olefination for initial C-C bond formation between aldehydes and benzylic-sulfones. Palladium-catalyzed Meinwald rearrangement was used as a key step for the obtainment of ketone intermediates, which on base promoted intramolecular cyclization afforded the desired isocoumarins. The developed method has paved the way for hitherto unknown 3-glycosyl isocoumarins in general and 3-glucosyl isocoumarins in particular wherein the glucosyl moiety is attached to the pyrone ring of isocoumarin framework, for the first time." @default.
- W2549274613 created "2016-11-30" @default.
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- W2549274613 date "2016-12-06" @default.
- W2549274613 modified "2023-10-04" @default.
- W2549274613 title "Convenient Synthesis of 3-Glycosylated Isocoumarins" @default.
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- W2549274613 doi "https://doi.org/10.1002/ejoc.201601264" @default.
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