Matches in SemOpenAlex for { <https://semopenalex.org/work/W2549671856> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2549671856 endingPage "329" @default.
- W2549671856 startingPage "325" @default.
- W2549671856 abstract "The local structure of the Cu$^{2+}$ center in mixed alkali cadmium phosphate (10Li$_2$O-10Na$_2$O-20CdO-59.5P$_2$O$_5$) glass is theoretically investigated from the optical spectral data and high-order perturbation formulas of the electron paramagnetic resonance (EPR) parameters ($g$-factors $g_{|}, g_{bot}$ and the hyperfine structure constants $A_{|}, A_{bot}$) for a 3d$^9$ ion in a tetragonally elongated octahedron. In these formulas, the ligand orbital and spin-orbit coupling contributions are taken into account based on the cluster approach in view of moderate covalency. The required crystal-field parameters are determined by the superposition model. According to the calculations, the impurity-ligand distances parallel and perpendicular to the C$_4$ axis of [CuO$_6$]$^{10-}$ cluster are found to be, respectively, $R_{|} approx 2.051$ AA, and $R_{bot}approx 2.029$ AA, due to Jahn-Teller effect. Based on the above local structure data, the optical spectra are satisfactorily interpreted. The signs of $ A_{|} $ and $ A_{bot} $ for the Cu$^{2+}$ center are suggested in the discussion." @default.
- W2549671856 created "2016-11-30" @default.
- W2549671856 creator A5029265077 @default.
- W2549671856 creator A5037375130 @default.
- W2549671856 creator A5038727912 @default.
- W2549671856 creator A5077936202 @default.
- W2549671856 creator A5083867923 @default.
- W2549671856 date "2016-01-01" @default.
- W2549671856 modified "2023-09-26" @default.
- W2549671856 title "Theoretical studies of the local structure and the epr parameters for tetragonal Cu2+ center in mixed alkali cadmium phosphate glasses" @default.
- W2549671856 cites W1510913788 @default.
- W2549671856 cites W2132905138 @default.
- W2549671856 hasPublicationYear "2016" @default.
- W2549671856 type Work @default.
- W2549671856 sameAs 2549671856 @default.
- W2549671856 citedByCount "0" @default.
- W2549671856 crossrefType "journal-article" @default.
- W2549671856 hasAuthorship W2549671856A5029265077 @default.
- W2549671856 hasAuthorship W2549671856A5037375130 @default.
- W2549671856 hasAuthorship W2549671856A5038727912 @default.
- W2549671856 hasAuthorship W2549671856A5077936202 @default.
- W2549671856 hasAuthorship W2549671856A5083867923 @default.
- W2549671856 hasConcept C115624301 @default.
- W2549671856 hasConcept C121332964 @default.
- W2549671856 hasConcept C131538251 @default.
- W2549671856 hasConcept C145148216 @default.
- W2549671856 hasConcept C164866538 @default.
- W2549671856 hasConcept C170751736 @default.
- W2549671856 hasConcept C178790620 @default.
- W2549671856 hasConcept C184779094 @default.
- W2549671856 hasConcept C185592680 @default.
- W2549671856 hasConcept C187961010 @default.
- W2549671856 hasConcept C192562407 @default.
- W2549671856 hasConcept C198091228 @default.
- W2549671856 hasConcept C198819137 @default.
- W2549671856 hasConcept C199360897 @default.
- W2549671856 hasConcept C2779463800 @default.
- W2549671856 hasConcept C41008148 @default.
- W2549671856 hasConcept C41999313 @default.
- W2549671856 hasConcept C46141821 @default.
- W2549671856 hasConcept C57805442 @default.
- W2549671856 hasConcept C71987851 @default.
- W2549671856 hasConcept C8010536 @default.
- W2549671856 hasConceptScore W2549671856C115624301 @default.
- W2549671856 hasConceptScore W2549671856C121332964 @default.
- W2549671856 hasConceptScore W2549671856C131538251 @default.
- W2549671856 hasConceptScore W2549671856C145148216 @default.
- W2549671856 hasConceptScore W2549671856C164866538 @default.
- W2549671856 hasConceptScore W2549671856C170751736 @default.
- W2549671856 hasConceptScore W2549671856C178790620 @default.
- W2549671856 hasConceptScore W2549671856C184779094 @default.
- W2549671856 hasConceptScore W2549671856C185592680 @default.
- W2549671856 hasConceptScore W2549671856C187961010 @default.
- W2549671856 hasConceptScore W2549671856C192562407 @default.
- W2549671856 hasConceptScore W2549671856C198091228 @default.
- W2549671856 hasConceptScore W2549671856C198819137 @default.
- W2549671856 hasConceptScore W2549671856C199360897 @default.
- W2549671856 hasConceptScore W2549671856C2779463800 @default.
- W2549671856 hasConceptScore W2549671856C41008148 @default.
- W2549671856 hasConceptScore W2549671856C41999313 @default.
- W2549671856 hasConceptScore W2549671856C46141821 @default.
- W2549671856 hasConceptScore W2549671856C57805442 @default.
- W2549671856 hasConceptScore W2549671856C71987851 @default.
- W2549671856 hasConceptScore W2549671856C8010536 @default.
- W2549671856 hasIssue "4" @default.
- W2549671856 hasLocation W25496718561 @default.
- W2549671856 hasOpenAccess W2549671856 @default.
- W2549671856 hasPrimaryLocation W25496718561 @default.
- W2549671856 hasRelatedWork W1593524760 @default.
- W2549671856 hasRelatedWork W1963802805 @default.
- W2549671856 hasRelatedWork W1979229613 @default.
- W2549671856 hasRelatedWork W1982614529 @default.
- W2549671856 hasRelatedWork W1988503964 @default.
- W2549671856 hasRelatedWork W2022064160 @default.
- W2549671856 hasRelatedWork W2031545289 @default.
- W2549671856 hasRelatedWork W2051910666 @default.
- W2549671856 hasRelatedWork W2055930254 @default.
- W2549671856 hasRelatedWork W2064136310 @default.
- W2549671856 hasRelatedWork W2088271685 @default.
- W2549671856 hasRelatedWork W2205401588 @default.
- W2549671856 hasRelatedWork W2287160154 @default.
- W2549671856 hasRelatedWork W2305765323 @default.
- W2549671856 hasRelatedWork W2469010900 @default.
- W2549671856 hasRelatedWork W2603159927 @default.
- W2549671856 hasRelatedWork W2916765202 @default.
- W2549671856 hasRelatedWork W3150244216 @default.
- W2549671856 hasRelatedWork W576143290 @default.
- W2549671856 hasRelatedWork W863207489 @default.
- W2549671856 hasVolume "62" @default.
- W2549671856 isParatext "false" @default.
- W2549671856 isRetracted "false" @default.
- W2549671856 magId "2549671856" @default.
- W2549671856 workType "article" @default.