Matches in SemOpenAlex for { <https://semopenalex.org/work/W2549849628> ?p ?o ?g. }
- W2549849628 endingPage "8263" @default.
- W2549849628 startingPage "8255" @default.
- W2549849628 abstract "Heterogeneous catalysis performed in wall-coated reactors and electrocatalysis require homogeneous catalytic coatings with high surface area and good accessibility of the active sites. Conventional coating methods necessitate the use of binder components that often block pores and active sites, which limits catalytic efficiency, and utilization of expensive active metals. We report an approach for the direct and binder-free synthesis of chemically, mechanically, and thermally stable catalytic coatings based on ordered mesoporous carbon films employed as catalyst support. The synthesis relies on the codeposition of a structure-directing agent and small clusters of polymeric carbon precursors along with ionic metal species on a substrate. A sequence of thermal treatments converts the polymer into partly graphitized carbon, decomposes the structure-directing agent, and converts the metal precursor into highly active nanoparticles. Syntheses and catalytic applications are exemplarily demonstrated for palladium on carbon, a system widely used in heterogeneous catalysis and electrocatalysis. The obtained catalysts provide significantly higher space–time yields in the selective gas-phase hydrogenation of butadiene than all reported Pd/C catalysts while at the same time retaining isothermal reactor conditions. Moreover, when they were tested in the electrocatalytic hydrogen evolution reaction (HER), the catalysts outperformed reported Pd/C catalysts by a factor of 3, which underlines the benefits of the developed binder-free catalyst system." @default.
- W2549849628 created "2016-11-30" @default.
- W2549849628 creator A5006358486 @default.
- W2549849628 creator A5046221386 @default.
- W2549849628 creator A5057901169 @default.
- W2549849628 creator A5065351769 @default.
- W2549849628 creator A5086227182 @default.
- W2549849628 creator A5090283867 @default.
- W2549849628 date "2016-11-11" @default.
- W2549849628 modified "2023-10-02" @default.
- W2549849628 title "Highly Active Binder-Free Catalytic Coatings for Heterogeneous Catalysis and Electrocatalysis: Pd on Mesoporous Carbon and Its Application in Butadiene Hydrogenation and Hydrogen Evolution" @default.
- W2549849628 cites W1193710312 @default.
- W2549849628 cites W1492066033 @default.
- W2549849628 cites W1964613054 @default.
- W2549849628 cites W1966033965 @default.
- W2549849628 cites W1972121081 @default.
- W2549849628 cites W1974102347 @default.
- W2549849628 cites W1982707973 @default.
- W2549849628 cites W1982836017 @default.
- W2549849628 cites W1983672069 @default.
- W2549849628 cites W1985640433 @default.
- W2549849628 cites W1986406465 @default.
- W2549849628 cites W1987409823 @default.
- W2549849628 cites W1987552136 @default.
- W2549849628 cites W1988651365 @default.
- W2549849628 cites W1997526344 @default.
- W2549849628 cites W1997656303 @default.
- W2549849628 cites W2002034886 @default.
- W2549849628 cites W2004190252 @default.
- W2549849628 cites W2005916189 @default.
- W2549849628 cites W2008067282 @default.
- W2549849628 cites W2017328744 @default.
- W2549849628 cites W2019645703 @default.
- W2549849628 cites W2020308314 @default.
- W2549849628 cites W2026870983 @default.
- W2549849628 cites W2030368764 @default.
- W2549849628 cites W2032714430 @default.
- W2549849628 cites W2034672716 @default.
- W2549849628 cites W2039044271 @default.
- W2549849628 cites W2039179403 @default.
- W2549849628 cites W2050120119 @default.
- W2549849628 cites W2050561856 @default.
- W2549849628 cites W2061006070 @default.
- W2549849628 cites W2063134554 @default.
- W2549849628 cites W2064469073 @default.
- W2549849628 cites W2065210839 @default.
- W2549849628 cites W2068623132 @default.
- W2549849628 cites W2070875786 @default.
- W2549849628 cites W2072604522 @default.
- W2549849628 cites W2072752561 @default.
- W2549849628 cites W2075904417 @default.
- W2549849628 cites W2077303396 @default.
- W2549849628 cites W2079122585 @default.
- W2549849628 cites W2087806882 @default.
- W2549849628 cites W2088033856 @default.
- W2549849628 cites W2092564464 @default.
- W2549849628 cites W2109330760 @default.
- W2549849628 cites W2119226489 @default.
- W2549849628 cites W2121103171 @default.
- W2549849628 cites W2143518016 @default.
- W2549849628 cites W2145897653 @default.
- W2549849628 cites W2146233877 @default.
- W2549849628 cites W2150925176 @default.
- W2549849628 cites W2151827450 @default.
- W2549849628 cites W2153873568 @default.
- W2549849628 cites W2155676979 @default.
- W2549849628 cites W2156517468 @default.
- W2549849628 cites W2159770322 @default.
- W2549849628 cites W2165174544 @default.
- W2549849628 cites W2193122003 @default.
- W2549849628 cites W2274291878 @default.
- W2549849628 cites W2316902873 @default.
- W2549849628 cites W2319546051 @default.
- W2549849628 cites W2319709903 @default.
- W2549849628 cites W2323775438 @default.
- W2549849628 cites W2340423559 @default.
- W2549849628 cites W2460147441 @default.
- W2549849628 doi "https://doi.org/10.1021/acscatal.6b02240" @default.
- W2549849628 hasPublicationYear "2016" @default.
- W2549849628 type Work @default.
- W2549849628 sameAs 2549849628 @default.
- W2549849628 citedByCount "24" @default.
- W2549849628 countsByYear W25498496282017 @default.
- W2549849628 countsByYear W25498496282018 @default.
- W2549849628 countsByYear W25498496282019 @default.
- W2549849628 countsByYear W25498496282020 @default.
- W2549849628 countsByYear W25498496282021 @default.
- W2549849628 countsByYear W25498496282022 @default.
- W2549849628 countsByYear W25498496282023 @default.
- W2549849628 crossrefType "journal-article" @default.
- W2549849628 hasAuthorship W2549849628A5006358486 @default.
- W2549849628 hasAuthorship W2549849628A5046221386 @default.
- W2549849628 hasAuthorship W2549849628A5057901169 @default.
- W2549849628 hasAuthorship W2549849628A5065351769 @default.
- W2549849628 hasAuthorship W2549849628A5086227182 @default.
- W2549849628 hasAuthorship W2549849628A5090283867 @default.
- W2549849628 hasConcept C104779481 @default.
- W2549849628 hasConcept C127413603 @default.