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- W2549984893 abstract "It has been established that cationic rhodium(I)/axially chiral biaryl bis(phosphine) complexes catalyze the asymmetric [2+2+2] cycloaddition of 1,6-enynes with electron-rich functionalized alkenes, enamides, and vinyl carboxylates, to produce the corresponding protected cyclohexenylamines and cyclohexenols. Interestingly, regioselectivity depends on structures of substrates. The present cycloaddition was successfully applied to the enantioselective total synthesis of (-)-porosadienone by using the amide moiety as a leaving group." @default.
- W2549984893 created "2016-11-30" @default.
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- W2549984893 date "2016-11-10" @default.
- W2549984893 modified "2023-10-16" @default.
- W2549984893 title "Asymmetric Synthesis of Protected Cyclohexenylamines and Cyclohexenols by Rhodium-Catalyzed [2+2+2] Cycloaddition" @default.
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- W2549984893 doi "https://doi.org/10.1002/anie.201608952" @default.
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