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• W2550023186 abstract "A macromolecular homopolymer (named as Homo-THEIC) was synthesized through self-etherification of tris(2-hydroxyethyl) isocyanurate (THEIC) molecules and used as charring agent. Its chemical structure was characterized by FTIR and 13C-NMR. The charring agent was mixed with ammonium polyphosphate (APP) and applied in flame retarded polypropylene (PP). Results of UL-94, LOI, and cone calorimeter test showed that the LOI of flame retarded PP can reach 32.8% and UL-94 V-0 rating can be achieved at 30 wt % loading. The heat release rate and smoke production rate during the combustion of PP were substantially reduced. TGA results indicated that the synergistic effect between APP and Homo-THEIC existed and the addition of intumescent flame retardant (IFR) dramatically enhanced the thermal stability of PP. According to the results of TGA, SEM, TG-FTIR, FTIR, and Raman, the char forming process of IFR can be separated into three stages: the formation of viscous phosphate ester (Tonset−330 °C), the expanding process along with the decomposition of phosphate ester and the release of a large amount of gases (330–480 °C), and the final formation of graphitic-like char without any expanding feature (480–670 °C). © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44663." @default.
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• W2550023186 date "2016-11-23" @default.
• W2550023186 modified "2023-10-18" @default.
• W2550023186 title "Synthesis of tris(2-hydroxyethyl) isocyanurate homopolymer and its application in intumescent flame retarded polypropylene" @default.
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• W2550023186 doi "https://doi.org/10.1002/app.44663" @default.
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