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- W2550809059 abstract "Photocatalytic water splitting is a natural but challenging chemical way of harnessing renewable solar power to generate clean hydrogen energy. Here we report a potential hydrogen-evolving photochemical molecular device based on a self-assembled ruthenium-palladium heterometallic coordination cage, incorporating multiple photo- and catalytic metal centres. The photophysical properties are investigated by absorption/emission spectroscopy, electrochemical measurements and preliminary DFT calculations and the stepwise electron transfer processes from ruthenium-photocentres to catalytic palladium-centres is probed by ultrafast transient absorption spectroscopy. The photocatalytic hydrogen production assessments reveal an initial reaction rate of 380 μmol h-1 and a turnover number of 635 after 48 h. The efficient hydrogen production may derive from the directional electron transfers through multiple channels owing to proper organization of the photo- and catalytic multi-units within the octahedral cage, which may open a new door to design photochemical molecular devices with well-organized metallosupramolecules for homogenous photocatalytic applications." @default.
- W2550809059 created "2016-11-30" @default.
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- W2550809059 date "2016-11-09" @default.
- W2550809059 modified "2023-10-12" @default.
- W2550809059 title "A metal-organic cage incorporating multiple light harvesting and catalytic centres for photochemical hydrogen production" @default.
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- W2550809059 doi "https://doi.org/10.1038/ncomms13169" @default.
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