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- W2550978075 abstract "Electrolysis of cuprous chloride is a critical step in the copperchlorine thermochemical cycle for hydrogen production, a novel process with the advantage of mild operating conditions and capability of recovery of low grade heat from nuclear reactors. This step can be achieved in solid polymer electrolyte reactor with either Nafion membrane or anion exchange membrane. In this paper, cell polarization experiments show that the reactor with Nafion 115 has a higher thermal stability than that of the AMX membrane for the bulk electrolysis. In the anode half cell reaction, effects of catalysts and mass transfer were studied on the thin film electrode on the rotating disk electrode (RDE). It was found that the active carbon Vulcan XC 72 has comparable activity towards the cuprous chloride oxidation with conventional electro- catalysts, such as Pt black, Pt/C and RuO2. Also, mass transfer was serious in the rate process in the anode." @default.
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- W2550978075 date "2009-10-02" @default.
- W2550978075 modified "2023-09-27" @default.
- W2550978075 title "Low Temperature Electrochemical Production of Hydrogen from the Hybrid Copper-Chlorine Thermochemical Cycle" @default.
- W2550978075 doi "https://doi.org/10.1088/1938-5862/19/10/95" @default.
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