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- W2551243397 abstract "Abstract The heteroyclic ligand di-2-pyridyl ketone oxime (dpko) was reacted with MBr2·xH2O (M = Cu, Zn), affording several novel complexes. [Cu2(dpko)2Br4][CuBr4] and Zn(dpko)Br2 complexes are analogs of previously reported chloride complexes, and both are structurally and spectroscopically similar to the chloride analogs, [Cu2(dpko)2Cl4]Cl2 and Zn(dpko)Cl2; however, [Cu2(dpko)2Br4][CuBr4] crystallizes as the [CuBr4]2 − salt, while Zn(dpko)X2 exhibits a previously unreported disorder at the oxime site, which we now believe to also found to be present in the Zn(dpko)Cl2 analog. We also present EPR data for both [Cu2(dpko)2Br4][CuBr4] and [Cu2(dpko)2Cl4]Cl2." @default.
- W2551243397 created "2016-11-30" @default.
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- W2551243397 date "2016-12-01" @default.
- W2551243397 modified "2023-09-27" @default.
- W2551243397 title "Crystal structure and magnetic properties of di-copper and di-zinc complexes with di-2-pyridyl ketone oxime" @default.
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- W2551243397 doi "https://doi.org/10.1016/j.inoche.2016.11.003" @default.
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