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- W2551524940 abstract "Abstract An isolable heterocyclic silylene ( 4 ) with two different π‐donating substituents, namely a classical amino group and a more electropositive and stronger carbon‐based π‐donating phosphonium ylide, was synthesized and fully characterized. The combination of these two different π‐donating substituents confers high thermal stability and an unusual nucleophilic character on silylene 4 . Therefore, silylene 4 behaves as a strong donor ligand toward transition metals with a donating character comparable to N ‐heterocyclic carbenes, in contrast to classical N ‐heterocyclic silylenes, which generally present a weak donating character." @default.
- W2551524940 created "2016-11-30" @default.
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- W2551524940 date "2016-11-25" @default.
- W2551524940 modified "2023-10-18" @default.
- W2551524940 title "Cyclic Amino(Ylide) Silylene: A Stable Heterocyclic Silylene with Strongly Electron-Donating Character" @default.
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- W2551524940 doi "https://doi.org/10.1002/anie.201609899" @default.
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