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• W2551567213 endingPage "189" @default.
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• W2551567213 abstract "A phosphorous-modified γ-Al2O3 (P-Al2O3), where γ-Al2O3 support was prepared by sol-gel method with a high surface area of ∼350 m2/g, has been applied for a preparation of cobalt-supported Co/P-Al2O3 catalysts. The Co/P-Al2O3 catalysts having a different P/Al molar ratio were investigated to elucidate the roles of phosphorous species on the γ-Al2O3 to the catalytic stability and product distribution for CO hydrogenation to hydrocarbons. The γ-Al2O3 surface was partially transformed to aluminum phosphates after phosphorous modification, and the newly formed aluminum phosphate phases simultaneously altered the surface hydrophilicity and cobalt dispersion as well. The partial formation of tridymite aluminum phosphate (AlPO4) phases on the P-Al2O3 support eventually enhanced the dispersion of the supported cobalt crystallites and suppressed the aggregation of cobalt nanoparticles by forming the strongly interacted cobalt crystallites on the P-Al2O3 surfaces. The phosphorous-modified Fischer-Tropsch synthesis (FTS) catalyst also significantly suppressed heavy hydrocarbon depositions due to an increased surface hydrophilicity originated from partially formed SiO2-like tridymite AlPO4 surfaces. A higher stability of the Co/P-Al2O3 catalyst at an optimal phosphorous content in the range of 0.5–1.0 mol% was attributed to homogeneously distributed cobalt crystallites and less deposition of heavy hydrocarbons by forming macro-emulsion droplets with the help of trace amount of alcohols formed during FTS reaction. This was confirmed by in-situ analysis of adsorbed intermediates with surface hydrophilicity and some surface characterizations such as crystallite size, reducibility, and electronic state of the supported cobalt nanoparticles." @default.
• W2551567213 created "2016-11-30" @default.
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• W2551567213 date "2017-01-01" @default.
• W2551567213 modified "2023-10-02" @default.
• W2551567213 title "Roles of phosphorous-modified Al2O3 for an enhanced stability of Co/Al2O3 for CO hydrogenation to hydrocarbons" @default.
• W2551567213 cites W1007071703 @default.
• W2551567213 cites W165274381 @default.
• W2551567213 cites W1965941026 @default.
• W2551567213 cites W1966329772 @default.
• W2551567213 cites W1968559518 @default.
• W2551567213 cites W1970673114 @default.
• W2551567213 cites W1971467511 @default.
• W2551567213 cites W1971751755 @default.
• W2551567213 cites W1974078145 @default.
• W2551567213 cites W1974226595 @default.
• W2551567213 cites W1976706415 @default.
• W2551567213 cites W1977805930 @default.
• W2551567213 cites W1978030017 @default.
• W2551567213 cites W1978891011 @default.
• W2551567213 cites W1979514288 @default.
• W2551567213 cites W1981700937 @default.
• W2551567213 cites W1984435729 @default.
• W2551567213 cites W1985892429 @default.
• W2551567213 cites W1985962879 @default.
• W2551567213 cites W1989232385 @default.
• W2551567213 cites W1990002699 @default.
• W2551567213 cites W1996273621 @default.
• W2551567213 cites W1999938807 @default.
• W2551567213 cites W2000692889 @default.
• W2551567213 cites W2008038746 @default.
• W2551567213 cites W2009641312 @default.
• W2551567213 cites W2015124413 @default.
• W2551567213 cites W2015776157 @default.
• W2551567213 cites W2016507462 @default.
• W2551567213 cites W2018993297 @default.
• W2551567213 cites W2024057921 @default.
• W2551567213 cites W2026203227 @default.
• W2551567213 cites W2027314172 @default.
• W2551567213 cites W2030903543 @default.
• W2551567213 cites W2031359079 @default.
• W2551567213 cites W2032344141 @default.
• W2551567213 cites W2036284779 @default.
• W2551567213 cites W2036708776 @default.
• W2551567213 cites W2040369116 @default.
• W2551567213 cites W2040632963 @default.
• W2551567213 cites W2041043995 @default.
• W2551567213 cites W2048395652 @default.
• W2551567213 cites W2055393736 @default.
• W2551567213 cites W2056611779 @default.
• W2551567213 cites W2060314855 @default.
• W2551567213 cites W2060428253 @default.
• W2551567213 cites W2064039979 @default.
• W2551567213 cites W2064739517 @default.
• W2551567213 cites W2065296814 @default.
• W2551567213 cites W2066003592 @default.
• W2551567213 cites W2066901211 @default.
• W2551567213 cites W2067453873 @default.
• W2551567213 cites W2068103283 @default.
• W2551567213 cites W2069113466 @default.
• W2551567213 cites W2072710632 @default.
• W2551567213 cites W2080240511 @default.
• W2551567213 cites W2080445005 @default.
• W2551567213 cites W2082015650 @default.
• W2551567213 cites W2084019341 @default.
• W2551567213 cites W2084109175 @default.
• W2551567213 cites W2085179439 @default.
• W2551567213 cites W2087454902 @default.
• W2551567213 cites W2091882238 @default.
• W2551567213 cites W2092928677 @default.
• W2551567213 cites W2094704195 @default.
• W2551567213 cites W2098476185 @default.
• W2551567213 cites W2117523245 @default.
• W2551567213 cites W2137064052 @default.
• W2551567213 cites W2146434650 @default.
• W2551567213 cites W2164905204 @default.
• W2551567213 cites W2194083794 @default.
• W2551567213 cites W2276934042 @default.
• W2551567213 cites W2292748136 @default.
• W2551567213 cites W2314327342 @default.
• W2551567213 cites W2319709669 @default.
• W2551567213 cites W4229954090 @default.
• W2551567213 cites W4301025388 @default.
• W2551567213 cites W4368059517 @default.
• W2551567213 doi "https://doi.org/10.1016/j.molcata.2016.11.013" @default.
• W2551567213 hasPublicationYear "2017" @default.
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