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- W2551907636 abstract "A neutral tripodal tris(ferrocenylurea)anion receptor has been designedthat can electrochemically andoptically recognize sulfate and phosphateanions. The binding of the tetrahedralanion induced distinct cathodicshifts of the ferrocene/ferroceniumredox couple in chloroform, whereasthe UV/Vis spectrum of the receptorshowed an increase in the d–d transitionband upon addition of sulfate ions.Furthermore, the anion complexes(TBA)2·ACHTUNGTRENUNG[SO4 L]·H2O (1) and TBAACHTUNGTRENUNG[F L] (2; TBA=tetrabutylammoniumion) were isolated. Crystal structuralanalyses showed that the receptor inthe two 1:1 (host/guest) complexes encapsulatedsulfate or fluoride ions inthe tripodal cavity through multiple hydrogenbonds. 1H NMR spectroscopicand ESI mass-spectrometric analysisrevealed strong sulfate and fluoridebinding in solution." @default.
- W2551907636 created "2016-11-30" @default.
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- W2551907636 date "2011-01-01" @default.
- W2551907636 modified "2023-09-23" @default.
- W2551907636 title "An Electrochemical and Optical Anion Chemosensor Based on Tripodal Tris(ferrocenylurea)" @default.
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