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- W2551924488 abstract "The bridged peri-aroylnaphthalene compounds having 1,3-benzendioxy-hinge units were newly synthesized and the spatial organization in solution was characterized in comparison with isomeric derivatives having 1,2-benzenedioxy-hinge unit and a non-bridged analogue. 1,2Benzenedioxy and 1,3-benzendioxy-hinge units, which connect the edge carbon atoms of aroyl groups, afford the distinct difference in rotation ability of benzene ring of aroyl groups. The sharpness/broadness and the non-equivalency of H NMR signals of aromatic protons demonstrate the highly congested and hinge-depending spatial organization of these bridged peri-aroylnaphthalene molecules. Furthermore, the significant magnetic field deviation of the signals in H NMR spectra proves the presence of effective induced magnetic field especially for the middle proton at the 2-position of the 1,3-benzenedioxy unit." @default.
- W2551924488 created "2016-11-30" @default.
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- W2551924488 date "2015-01-01" @default.
- W2551924488 modified "2023-09-27" @default.
- W2551924488 title "SPATIAL ORGANIZATION OF BRIDGED peri-AROYLNAPHTHALENE COMPOUNDS HAVING 1,2- OR 1,3-BENZENEDIOXY-HINGE MOIETY IN SOLUTION" @default.
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