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- W2553304225 abstract "Polyethylene glycols (PEGs) with different molecular weights ( M w = 200, 400, 1000) were phosphorylated to their bis ‐diphenyl phosphinite derivatives as stable solids which are melted in the range 140–160°C. These phosphorylated PEGs were used as ligands and reducing agents to generate nano‐Pd(0) catalysts in 2.5–8.3 nm. The nano‐Pd(0) particles supported on phosphorylated PEG 200 were applied for the efficient Heck–Mizoroki carbon–carbon coupling reactions of ArX (X = Cl, Br, I) at 80–100°C under solvent‐free conditions and for the Suzuki–Miyaura coupling reaction in ethanol at 70°C. The catalyst was recycled easily and reused for several runs. Copyright © 2013 John Wiley & Sons, Ltd." @default.
- W2553304225 created "2016-11-30" @default.
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- W2553304225 date "2013-07-19" @default.
- W2553304225 modified "2023-10-15" @default.
- W2553304225 title "Phosphorylated PEG (PPEG) as a new support for generation of nano-Pd(0): application to the Heck-Mizoroki and Suzuki-Miyaura coupling reactions" @default.
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- W2553304225 doi "https://doi.org/10.1002/aoc.3002" @default.
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