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- W2553350557 abstract "Abstract A new heterogeneous NHC catalyst (1-Pd) was obtained by the post-synthetic modification of an azolium-containing metal-organic framework (1) which was synthesized by solvothermal reaction of 1,3-bis(4-carboxyphenyl)imidazolium chloride (H2L+Cl−) and Zn(NO3)2·6H2O. This new material, 1-Pd, was characterized by PXRD, TGA, SEM, TEM, 1H and 13C NMR, FTIR and XPS measurements. This catalyst exhibited an excellent activity for both Sonogashira cross-coupling and Knoevenagel condensation reaction retaining its catalytic and uniform distribution of the active sites, palladium (II) anchored on N-heterocyclic carbene (NHC-Pd(II)), for at least four cycles without losing its structural integrity." @default.
- W2553350557 created "2016-11-30" @default.
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- W2553350557 date "2016-12-01" @default.
- W2553350557 modified "2023-10-17" @default.
- W2553350557 title "Post-synthetic modified MOF for Sonogashira cross-coupling and Knoevenagel condensation reactions" @default.
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- W2553350557 doi "https://doi.org/10.1016/j.jcat.2016.10.015" @default.
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