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- W2553512712 abstract "Abstract The search for efficient and selective routes for the synthesis of chiral aminocyclopropane derivatives is of great interest and importance as these structures are important components of biologically active natural products and pharmaceuticals. We herein report the enantioselective intermolecular hydroamination of substituted cyclopropenes with various amines catalyzed by chiral half‐sandwich rare‐earth‐metal complexes. This method constitutes a 100 % atom‐efficient route for the synthesis of a variety of chiral α‐aminocyclopropane derivatives in high yields (up to 96 %) and excellent stereoselectivity (up to >20:1 d.r. and 99 % ee ) under mild reaction conditions (25 °C)." @default.
- W2553512712 created "2016-11-30" @default.
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- W2553512712 date "2016-11-11" @default.
- W2553512712 modified "2023-10-11" @default.
- W2553512712 title "Synthesis of Chiral Aminocyclopropanes by Rare-Earth-Metal-Catalyzed Cyclopropene Hydroamination" @default.
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- W2553512712 doi "https://doi.org/10.1002/anie.201609853" @default.
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