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• W2553559144 endingPage "265" @default.
• W2553559144 startingPage "261" @default.
• W2553559144 abstract "Using cyclic voltammetry (CV), in-situ scanning tunneling microscopy (STM) and electrochemical quartz crystal microbalance (EQCM) the initial stages of lithium deposition on Au(111) from a solution of lithium bis(trifluoromethylsulfonyl)imide in the commercially available ionic liquid 1-methyl-1-propylpiperidinium bis(trifluoromethylsulfonyl)imide (MPPipTFSI) were investigated. We could identify three distinct cathodic peaks in the potential range from 0 to −2.5 V (vs. Pt quasi-reference electrode), corresponding to different lithium deposition modes. While in the potential region of the under-potential deposition (UPD) (−1.2 to −1.8 V) the growth of monoatomic high islands (300–370 pm) takes place, Li bulk deposition occurs at potentials <−2.3 V. Finally, the third peak at 0 V, which only appears after a previous bulk deposition, is connected to a strand-like growth of lithium at (111) terraces with a uniform orientation over the whole substrate. Interestingly, once reaching a step-edge, the one-dimensional growth continues into the electrolyte, indicating the initial stages of Li dendrite formation." @default.
• W2553559144 created "2016-11-30" @default.
• W2553559144 creator A5013318469 @default.
• W2553559144 creator A5062902954 @default.
• W2553559144 creator A5066960989 @default.
• W2553559144 date "2016-12-20" @default.
• W2553559144 modified "2023-09-25" @default.
• W2553559144 title "Lithium Deposition from a Piperidinium-based Ionic Liquid: Rapping Dendrites on the Knuckles" @default.
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• W2553559144 doi "https://doi.org/10.1002/celc.201600730" @default.
• W2553559144 hasPublicationYear "2016" @default.
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