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- W2553559256 abstract "Abstract In this study, the effect of Zn 2+ ions non-stoichiometry on the crystal structure, densification, microstructure, ionic polarizability and microwave dielectric properties of Li 2 ZnTi 3 O 8 ceramics were investigated. The non-stoichiometric Li 2 Zn 1+x Ti 3 O 8 compositions ( − 0.04 ≤ x ≤ 0.06 ) were prepared by the conventional solid state ceramic route. The evolution of the unit cell parameter and cation ordering were investigated employing XRD. The elemental analysis and microstructure of Li 2 Zn 1+x Ti 3 O 8 specimens were studied by EDX and SEM, respectively. It was found that a slight Zn 2+ ions excess improves density and microwave dielectric properties, while the deficiency of Zn 2+ ions brings deterioration of the properties. When x = 0.06, well relative density of 95.1%, uniform grains in microstructure without any second phase and best microwave dielectric properties of e r = 25.5, Q × f = 63000 GHz, τ f = −18 ppm/°C were achieved in non-stoichiometric Li 2 Zn 1.06 Ti 3 O 8 ceramic rather than other non-stoichiometric and stoichiometric compositions." @default.
- W2553559256 created "2016-11-30" @default.
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- W2553559256 date "2017-02-01" @default.
- W2553559256 modified "2023-09-27" @default.
- W2553559256 title "Effect of zinc ions non-stoichiometry on the microstructure and microwave dielectric properties of Li2ZnTi3O8 ceramics" @default.
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- W2553559256 doi "https://doi.org/10.1016/j.jallcom.2016.10.326" @default.
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