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• W2553561120 abstract "A copper-catalyzed oxidative dearomatization/spirocyclization of indole-2-carboxamides using tert-butyl hydroperoxide (TBHP) as the oxidant has been developed that provides rapid and efficient access to C2-spiro-pseudoindoxyls. Two of the sp2 C–H bonds are functionalized during the reaction process, and the reaction likely proceeds via the formation of a highly reactive 3H-indol-3-one intermediate followed by aromatic electrophilic substitution with the N-aryl ring of the amide moiety." @default.
• W2553561120 created "2016-11-30" @default.
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• W2553561120 date "2016-11-14" @default.
• W2553561120 modified "2023-09-27" @default.
• W2553561120 title "Copper-Catalyzed Oxidative Dearomatization/Spirocyclization of Indole-2-Carboxamides: Synthesis of 2-Spiro-pseudoindoxyls" @default.
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• W2553561120 doi "https://doi.org/10.1021/acs.orglett.6b03131" @default.
• W2553561120 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27934344" @default.
• W2553561120 hasPublicationYear "2016" @default.
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