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• W2553562240 endingPage "e3648" @default.
• W2553562240 startingPage "e3648" @default.
• W2553562240 abstract "Neutral half-sandwich η6-p-cymene ruthenium(II) complexes of general formula [Ru(η6-p-cymene)Cl(L)] (HL = monobasic O, N bidendate benzoylhydrazone ligand) have been synthesized from the reaction of [Ru(η6-p-cymene)(μ-Cl)Cl]2 with acetophenone benzoylhydrazone ligands. All the complexes have been characterized using analytical and spectroscopic (Fourier transform infrared, UV–visible, 1H NMR, 13C NMR) techniques. The molecular structures of three of the complexes have been determined using single-crystal X-ray diffraction, indicating a pseudo-octahedral geometry around the ruthenium(II) ion. All the ruthenium(II) arene complexes were explored as catalysts for transfer hydrogenation of a wide range of aromatic, cyclic and aliphatic ketones with 2-propanol using 0.1 mol% catalyst loading, and conversions of up to 100% were obtained. Further, the influence of other variables on the transfer hydrogenation reaction, such as base, temperature, catalyst loading and substrate scope, was also investigated." @default.
• W2553562240 created "2016-11-30" @default.
• W2553562240 creator A5020549391 @default.
• W2553562240 creator A5040870907 @default.
• W2553562240 date "2016-11-17" @default.
• W2553562240 modified "2023-09-27" @default.
• W2553562240 title "Transfer hydrogenation of ketones catalysed by half-sandwich (η⁶ -<i>p</i> -cymene) ruthenium(II) complexes incorporating benzoylhydrazone ligands" @default.
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• W2553562240 doi "https://doi.org/10.1002/aoc.3648" @default.
• W2553562240 hasPublicationYear "2016" @default.
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