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- W2553586317 abstract "MoS2 with (001) plane supported on carbon nanospheres (CNs) has been successfully synthesized by a facile solvothermal process. The effect of solvent and temperature on the growth of MoS2/CNs has been investigated, respectively. XRD results show that (001) plane of MoS2 was synthesized when using mixture solvent of N, N-dimethylformamide (DMF) and H2O. The electrochemical measurements show that MoS2/CNs samples with (001) plane have the enhanced hydrogen evolution reaction (HER) activity than MoS2/CNs without (001) plane. The effect of solvothermal temperature on (001) plane of MoS2 has been investigated. XRD results demonstrate the different interlayer spacing of 9.7 Å, 9.8 Å and 9.4 Å of (001) plane corresponding to 160, 200 and 240 °C, respectively, which may affect the electronic structure of MoS2 and bring different HER activity. TEM reveals the good interface adhesion between MoS2 and CNs at 200 °C, which may provide better conductivity and faster electron transfer rate. MoS2/CNs with the largest (001) distance obtained at 200 °C has the better HER activity than other samples synthesized at other temperatures. Therefore, tuning (001) plane of MoS2 under optimized conditions including solvent and temperature may be a facile way to prepare excellent HER electrocatalysts." @default.
- W2553586317 created "2016-11-30" @default.
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- W2553586317 date "2017-01-01" @default.
- W2553586317 modified "2023-10-16" @default.
- W2553586317 title "Activating MoS2/CNs by tuning (001) plane as efficient electrocatalysts for hydrogen evolution reaction" @default.
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- W2553586317 doi "https://doi.org/10.1016/j.ijhydene.2016.10.145" @default.
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