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- W2553692257 abstract "A novel reaction based on synergistic catalysis, combining palladium- and organocatalysis has been developed. The palladium catalyst activates vinyl benzoxazinanones via a decarboxylation to undergo a [4+2] cycloaddition with iminium-ion activated α,β-unsaturated aldehydes. The reaction is demonstrated to proceed for a number of combinations of vinyl benzoxazinanones reacting with α,β-unsaturated aldehydes, providing highly substituted vinyl tetrahydroquinolines in good to high yields, and excellent enantio- and diastereoselectivities (>98 % ee and >20:1 d.r.). The palladium catalyst used in the synergistic catalysis can be re-used in a one-pot sequential coupling reaction with an aromatic boronic acid forming the coupling product in 95 % yield, >20:1 d.r. and 99 % ee." @default.
- W2553692257 created "2016-11-30" @default.
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- W2553692257 date "2016-11-07" @default.
- W2553692257 modified "2023-10-01" @default.
- W2553692257 title "Decarboxylative [4+2] Cycloaddition by Synergistic Palladium and Organocatalysis" @default.
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- W2553692257 doi "https://doi.org/10.1002/anie.201607788" @default.
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