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- W2553918530 abstract "Abstract A new Cr-containing tungstophosphate [(Cr(H2O)2)3(H2P2W12O48)3]27 − (1a) was prepared via simple, one-pot reaction method, which was isolated as hydrated potassium salt, K4[H23(Cr(H2O)2)3(H2P2W12O48)3]·34H2O (1). Compound 1 was characterized by single-crystal X-ray diffraction, FT-IR, UV-vis, elemental analyses, thermal analysis, electrochemistry and electrospray ionization mass spectrometry. Polyoxoanion 1a is composed of three {P2W12} subunits linked by three {Cr(H2O)2} bridges alternately, forming a ring in a corner-sharing mode. Moreover, variable temperature magnetic susceptibility indicates that 1 shows antiferromagnetic behavior." @default.
- W2553918530 created "2016-11-30" @default.
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- W2553918530 date "2017-01-01" @default.
- W2553918530 modified "2023-09-27" @default.
- W2553918530 title "A new ring-shaped Cr-containing tungstophosphate based on [H 2 P 2 W 12 O 48 ] 12−" @default.
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- W2553918530 doi "https://doi.org/10.1016/j.inoche.2016.11.010" @default.
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