Matches in SemOpenAlex for { <https://semopenalex.org/work/W2554039712> ?p ?o ?g. }
- W2554039712 endingPage "766" @default.
- W2554039712 startingPage "762" @default.
- W2554039712 abstract "Protonation of trans-1,2-bis(4-pyridyl)ethylene (4,4'-bpe) with dilute sulfuric acid (33 %) afforded a protonated adduct [{4,4'-bpe⋅2 H+ }2 {HSO4 }-2 {SO4 }-2 {H2 O}2 ] (1). The neighboring olefinic bond in 1 is in a suitable range (3.931-4.064 Å) to undergo a photochemical [2+2] cycloaddition reaction. Upon irradiation with UV light (365 nm), 1 undergoes a molecular sliding involving the 4,4'-bpe⋅2 H+ units, affording 2, stabilized through OSO4 ⋅⋅⋅π interactions. Heating 1 to 50° C leads to a 3D hydrogen-bonded organic framework (HOF) (3). This process occurs through thermal dissociation of the bisulfate anion. Diffusion of iodine through the crystal lattice of 1 and 3 enables the reduction of sulfate to bisulfate, affording a 1D hydrogen-bonded chain (4). Solid-state 13 C CPMAS NMR, IR, DSC, and powder XRD studies further support stimuli-responsive structural tuning through crystal-to-crystal transformation. All these conversions occur with significant translational and rotational movements along with a series of bond-breaking and bond-forming processes." @default.
- W2554039712 created "2016-11-30" @default.
- W2554039712 creator A5008238569 @default.
- W2554039712 creator A5010356907 @default.
- W2554039712 creator A5019652364 @default.
- W2554039712 creator A5031589756 @default.
- W2554039712 creator A5033263659 @default.
- W2554039712 creator A5055541841 @default.
- W2554039712 date "2016-12-15" @default.
- W2554039712 modified "2023-10-18" @default.
- W2554039712 title "Structural Tuning of Anion-Templated Motifs with External Stimuli through Crystal-to-Crystal Transformation" @default.
- W2554039712 cites W1582367237 @default.
- W2554039712 cites W1964236078 @default.
- W2554039712 cites W1964557806 @default.
- W2554039712 cites W1964841819 @default.
- W2554039712 cites W1965685796 @default.
- W2554039712 cites W1970290350 @default.
- W2554039712 cites W1970582627 @default.
- W2554039712 cites W1971405072 @default.
- W2554039712 cites W1980300092 @default.
- W2554039712 cites W1985182159 @default.
- W2554039712 cites W1998144577 @default.
- W2554039712 cites W2000753651 @default.
- W2554039712 cites W2001309501 @default.
- W2554039712 cites W2005683669 @default.
- W2554039712 cites W2014558015 @default.
- W2554039712 cites W2020620422 @default.
- W2554039712 cites W2023578884 @default.
- W2554039712 cites W2025416022 @default.
- W2554039712 cites W2027786410 @default.
- W2554039712 cites W2030045664 @default.
- W2554039712 cites W2030180603 @default.
- W2554039712 cites W2032127032 @default.
- W2554039712 cites W2032758048 @default.
- W2554039712 cites W2045102664 @default.
- W2554039712 cites W2054568135 @default.
- W2554039712 cites W2056191603 @default.
- W2554039712 cites W2061635953 @default.
- W2554039712 cites W2061854907 @default.
- W2554039712 cites W2065147813 @default.
- W2554039712 cites W2072836010 @default.
- W2554039712 cites W2073672728 @default.
- W2554039712 cites W2073828664 @default.
- W2554039712 cites W2080907201 @default.
- W2554039712 cites W2082723030 @default.
- W2554039712 cites W2084533527 @default.
- W2554039712 cites W2085574160 @default.
- W2554039712 cites W2090513161 @default.
- W2554039712 cites W2090571967 @default.
- W2554039712 cites W2092557528 @default.
- W2554039712 cites W2093479080 @default.
- W2554039712 cites W2093883144 @default.
- W2554039712 cites W2093895579 @default.
- W2554039712 cites W2094401330 @default.
- W2554039712 cites W2096869284 @default.
- W2554039712 cites W2101281024 @default.
- W2554039712 cites W2106304091 @default.
- W2554039712 cites W2118187909 @default.
- W2554039712 cites W2118466258 @default.
- W2554039712 cites W2129065971 @default.
- W2554039712 cites W2133751028 @default.
- W2554039712 cites W2136309013 @default.
- W2554039712 cites W2147440332 @default.
- W2554039712 cites W2149381236 @default.
- W2554039712 cites W2151037107 @default.
- W2554039712 cites W2154112901 @default.
- W2554039712 cites W2154916513 @default.
- W2554039712 cites W2162396552 @default.
- W2554039712 cites W2163280199 @default.
- W2554039712 cites W2169935051 @default.
- W2554039712 cites W2170188840 @default.
- W2554039712 cites W2313907882 @default.
- W2554039712 cites W2314670264 @default.
- W2554039712 cites W2319228557 @default.
- W2554039712 cites W2319311343 @default.
- W2554039712 cites W2322893967 @default.
- W2554039712 cites W2341124026 @default.
- W2554039712 cites W2531598381 @default.
- W2554039712 cites W2900879334 @default.
- W2554039712 cites W2952727565 @default.
- W2554039712 cites W3149826414 @default.
- W2554039712 cites W4206475933 @default.
- W2554039712 cites W4235589938 @default.
- W2554039712 cites W4242055491 @default.
- W2554039712 cites W4242797756 @default.
- W2554039712 cites W4246665523 @default.
- W2554039712 cites W4247586792 @default.
- W2554039712 cites W4254204039 @default.
- W2554039712 cites W979441040 @default.
- W2554039712 doi "https://doi.org/10.1002/chem.201604542" @default.
- W2554039712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27879018" @default.
- W2554039712 hasPublicationYear "2016" @default.
- W2554039712 type Work @default.
- W2554039712 sameAs 2554039712 @default.
- W2554039712 citedByCount "5" @default.
- W2554039712 countsByYear W25540397122017 @default.
- W2554039712 countsByYear W25540397122018 @default.
- W2554039712 countsByYear W25540397122021 @default.