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- W2554139500 abstract "As a continuation of our interest in thiosemicarbazones and their transition metal complexes, we report the synthetic and spectroscopic investigations of the thiosemicarbazone from p-dimethylaminobenzaldehyde, dmabTSC, and its metal complexes of Zn(II), Cd(II), Hg(II) and Cu(II). Elemental analysis and molar conductivity data suggest a bimetallic copper complex while the other complexes contain a single metal center as expected from the reaction stoichiometry. In all the complexes dmabTSC coordinates as a neutral bidentate ligand binding through the azomethine nitrogen and thiocarbonyl sulfur. The ligand and complexes are strongly fluorescent in DMSO but this luminescent is almost entirely quenched in dichloromethane. In general, the emission intensity of the complexes was less than that for the free dmabTSC." @default.
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- W2554139500 date "2008-01-01" @default.
- W2554139500 modified "2023-09-24" @default.
- W2554139500 title "THIOSEMICARBAZONE COMPLEXES OF GROUP 12 ELEMENTS. 1. AN INVESTIGATION OF THE THIOSEMICARBAZONE FROM p-DIMETHYLAMINOBENZALDEHYDE 1" @default.
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