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- W2554637162 abstract "2,4-Di-tert-butyl-5,6-dialkylpyrimidines were easily obtained in a one-step reaction from dialkyl ketones and pivalonitrile in the presence of triflic anhydride. pKa values determined show that these compounds can be used as highly sterically non-nucleophilic bases. It was applied to the synthesis of vinyl triflates in which the strong TfOH acid is formed. The results were compared with the obtained using commercially available 2,4,6-tri-tert-butylpyrimidine (TTBP)." @default.
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- W2554637162 date "2007-11-06" @default.
- W2554637162 modified "2023-10-18" @default.
- W2554637162 title "2,4-Di-tert-butil-5,6-dialkylpyrimidines: easily prepared alternative to non-nucleophilic hindered bases" @default.
- W2554637162 doi "https://doi.org/10.3998/ark.5550190.0008.g06" @default.
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