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- W2554879925 abstract "The title compound, [Zn(NCS) 2 (C 21 H 15 N 3 )], crystallizes with three independent complex molecules in the asymmetric unit. In each complex molecule, the Zn II atom is coordinated by three N atoms of a 4′-phenyl-2,2′:6′,2′′-terpyridine ligand, and by the N atoms of two NCS − anions. The Zn II atoms are therefore five-coordinate, ZnN 5 , with distorted square-pyramidal geometries. In the crystal, the three independent molecules are linked by a series of offset π–π interactions [intercentroid distances vary between 3.680 (5) and 3.791 (5) Å], forming columns along the a -axis direction. The columns are linked via C—H...S interactions, forming a fence-like arrangement parallel to the ab plane. A small region of disordered electron density was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C 71 , 9–18], but the formula mass and unit-cell characteristics were not taken into account during the refinement." @default.
- W2554879925 created "2016-11-30" @default.
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- W2554879925 date "2016-11-15" @default.
- W2554879925 modified "2023-10-16" @default.
- W2554879925 title "(4′-Phenyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)bis(thiocyanato-κN)zinc(II) unknown solvate" @default.
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- W2554879925 doi "https://doi.org/10.1107/s2414314616017582" @default.
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