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- W2555364560 abstract "The methylenation/hydrogenation cascade reaction of aldehydes or ketones through a domino process involving two ensuing steps in a single pot is realized. The compatibility of Matsubara's reagent and Wilkinson's complex give a combination that allows, under dihydrogen, the transformation of a carbonyl function into a methyl group. This new method is suitable to introduce an ethyl motif from aromatic and aliphatic aldehydes with total chemoselectivity and total retention of α-stereochemical purity. The developed procedure is also extended to the introduction of methyl groups from ketones." @default.
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- W2555364560 date "2016-11-07" @default.
- W2555364560 modified "2023-10-16" @default.
- W2555364560 title "Domino Methylenation/Hydrogenation of Aldehydes and Ketones by Combining Matsubara's Reagent and Wilkinson's Catalyst" @default.
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- W2555364560 doi "https://doi.org/10.1002/ejoc.201601137" @default.
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