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- W2555852085 abstract "A series of hierarchically structured porous polyureas are prepared through the polymerization of diisocyanate monomers and H2O via a one-step and template-free strategy. This simple archetypal reaction combines carbon dioxide foaming process and hyper-crosslinking reaction. The obtained hierarchically porous polyureas (HPUs) consist of micro- and mesopores created by hyper-crosslinking reaction, and macropores generated by carbon dioxide foaming process. The HPUs have a high surface area up to 483.3 m2/g, and large pore volume (0.76 cm3/g). Besides, the nitrogen-doped carbon materials prepared by pyrolyzing the HPUs show a high specific capacitance (209 F/g at 1.0 A/g) and good cycling stability (99.8% capacitance retention after 5000 cycles), demonstrating the advantages of the hierarchically porous structure and nitrogen-rich chemical composition of HPUs." @default.
- W2555852085 created "2016-11-30" @default.
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- W2555852085 date "2017-01-01" @default.
- W2555852085 modified "2023-10-15" @default.
- W2555852085 title "One-step preparation of hierarchically porous polyureas: Simultaneous foaming and hyper-crosslinking" @default.
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- W2555852085 doi "https://doi.org/10.1016/j.polymer.2016.11.002" @default.
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