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- W2556221011 abstract "Summary Modern society requires sustainable energy-storage systems to complement the fast-growing implementation of renewable sources. However, conventional batteries are based on the redox reactions of metals, which are constrained by material abundance, cost, and environmental concerns. As an alternative, quinone-based organic redox species represent one of the most promising electrode materials as a result of features including material sustainability, tailorable properties, and environmental benignity. Here, we report a systematic study on the electrochemical characteristics of quinones for organic flow batteries with a combined experimental and computational method. The redox properties of quinones were found to be strongly dependent on the molecular aromaticity and their electronic structures. In the prototype cell test, a naphthoquinone-based battery delivered a volumetric capacity of 20 Ah L −1 and reached an energy density of 60 Wh L −1 . Because quinones play a key role in bioelectrochemical processes, a fundamental understanding of their reaction mechanisms in electrochemical energy-storage devices can pave the path toward bio-inspired sustainable energy technologies." @default.
- W2556221011 created "2016-11-30" @default.
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- W2556221011 date "2016-11-01" @default.
- W2556221011 modified "2023-10-17" @default.
- W2556221011 title "Exploring Bio-inspired Quinone-Based Organic Redox Flow Batteries: A Combined Experimental and Computational Study" @default.
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- W2556221011 doi "https://doi.org/10.1016/j.chempr.2016.09.004" @default.
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