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- W2556421458 abstract "Telluro-niobatexNb2O5-(20-x)BaO-80TeO2 glass system was prepared by melt-quenching method. Elastic, structure, and optical properties of the glass systems were measured using ultrasonic velocity measurement, Raman spectroscopy and UV-Vis spectroscopy, respectively. Results showed that the longitudinal velocity, vL and shear velocity, vs and independent moduli, CL and µ steadily increased with Nb2O5. The related moduli such as bulk modulus, Ke and Young's modulus, Y and also Debye temperature, θD showed similar behavior to CL and µ. The increase of elastic moduliis suggested to be due to the increase of bridging oxygen (BO) via TeO4 tbp formation compared to non-brindging oxygen (NBO) which was confirmed by Raman spectroscopy and these results indicate the stabilizer effect of Nb2O5. Optical energy gap, Eopt was found to decrease with Nb2O5which is suggested to be due to smaller difference between HOMO and LUMO states of TeO4 tbp compared to that of TeO3 tp and the averaging effect of Eopt of constituent oxides. Meanwhile, Urbach energy, Eu decreased with Nb2O5 content indicating reduction in disorder of the glass structure." @default.
- W2556421458 created "2016-11-30" @default.
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- W2556421458 date "2015-01-01" @default.
- W2556421458 modified "2023-09-28" @default.
- W2556421458 title "EFFECT OF Nb2O5 NETWORK STABILIZER ON ELASTIC AND OPTICAL PROPERTIES OF xNb2O5-(20-x)BaO-80TeO2 TELLURITE GLASS SYSTEM" @default.
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