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- W2556550042 abstract "A series of glycosylation and alkylation reactions of 6-phenanthernyl-2-pyridone derivatives containing electron withdrawing and electron donating substituents at 4-position is reported. Regioselective 2-O-alkylated/glycosylated products were obtained exclusively, irrespective of the electronic nature of alkylating or the glycosyling agent. Glycosylation of with glucosyl/galactosyl and lactosyl bromides afforded ; ; and , respectively. Alkylation of with epichlorohydrin, propargyl, allyl bromides, and 3-chloropropanol resulted in compounds and , respectively. Deprotection of O-glycosylated products under conventional conditions provided the free glycosides ; ; ,; and , respectively. The minimal inhibitory concentration for some of the newly synthesized compounds showed high significant activity against Gram (+ve) and Gram (−ve) and antifungal activities. Among the screened compounds, the 4-trifluromethyl phenyl derivatives , , , , and exhibited strong antimicrobial activity." @default.
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- W2556550042 date "2016-01-25" @default.
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- W2556550042 title "<i>O</i>-Glycosylation/Alkylation and Antimicrobial Activity of 4,6-Diaryl-2-Oxonicotinonitrile Derivatives" @default.
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- W2556550042 doi "https://doi.org/10.1002/jhet.2593" @default.
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