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- W2556556027 abstract "Two electrodes for anodic water oxidation made by direct synthesis of inorganic catalysts onto conductive carbon fibre sheets are evaluated. As catalysts two Co- and Sb-containing phases were tested, that is, Co3Sb4O6F6 and the new compound CoSbO4. The compounds express large differences in their morphology: CoSbO4 grows as thin needles whereas Co3Sb4O6F6 grows as larger facetted crystals. Despite the smaller surface area the latter compound shows a better catalytic performance. When the compound Co3Sb4O6F6 was used it gave a low increase of +0.028 mV h−1 at an overpotential of η=472 mV after 10 h and a stability of +0.48 mV h−1 at an overpotential of η=488 mV after 60 h. The leakages of Co and Sb were negligible and only <0.001 at % Co and approximately 0.02 at % Sb were detected in the electrolyte." @default.
- W2556556027 created "2016-11-30" @default.
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- W2556556027 date "2016-11-10" @default.
- W2556556027 modified "2023-10-03" @default.
- W2556556027 title "Direct Synthesis of Two Inorganic Catalysts on Carbon Fibres for the Electrocatalytic Oxidation of Water" @default.
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- W2556556027 doi "https://doi.org/10.1002/chem.201603085" @default.
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