FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2556560417> ?p ?o ?g. }

• W2556560417 endingPage "12262" @default.
• W2556560417 startingPage "12254" @default.
• W2556560417 abstract "The structures of three solvated monovalent cation salts of the superweak anion B12F122- (Y2-), K2(SO2)6Y, Ag2(SO2)6Y, and Ag2(H2O)4Y, are reported and discussed with respect to previously reported structures of Ag+ and K+ with other weakly coordinating anions. The structures of K2(SO2)6Y and Ag2(SO2)6Y are isomorphous and are based on expanded cubic close-packed arrays of Y2- anions with M(OSO)6+ complexes centered in the trigonal holes of one expanded close-packed layer of B12 centroids (⊙). The K+ and Ag+ ions have virtually identical bicapped trigonal prism MO6F2 coordination spheres, with M-O distances of 2.735(1)-3.032(2) Å for the potassium salt and 2.526(5)-2.790(5) Å for the silver salt. Each M(OSO)6+ complex is connected to three other cationic complexes through their six μ-SO2-κ1O,κ2O' ligands. The structure of Ag2(H2O)4Y is unique [different from that of K2(H2O)4Y]. Planes of close-packed arrays of anions are offset from neighboring planes along only one of the linear ⊙···⊙···⊙ directions of the close-packed arrays, with [Ag(μ-H2O)2Ag(μ-H2O)2)]∞ infinite chains between the planes of anions. There are two nearly identical AgO4F2 coordination spheres, with Ag-O distances of 2.371(5)-2.524(5) Å and Ag-F distances of 2.734(4)-2.751(4) Å. This is only the second structurally characterized compound with four H2O molecules coordinated to a Ag+ ion in the solid state. Comparisons with crystalline H2O and SO2 solvates of other Ag+ and K+ salts of weakly coordinating anions show that (i) N[(SO2)2(1,2-C6H4)]-, BF4-, SbF6-, and Al(OC(CF3)3)4- coordinate much more strongly to Ag+ than does Y2-, (ii) SnF62- coordinates somewhat more strongly to K+ than does Y2-, and (iii) B12Cl122- coordinates to K+ about the same as, if not slightly weaker than, Y2-." @default.
• W2556560417 created "2016-11-30" @default.
• W2556560417 creator A5012947921 @default.
• W2556560417 creator A5025788864 @default.
• W2556560417 creator A5028808065 @default.
• W2556560417 creator A5046928138 @default.
• W2556560417 creator A5083391134 @default.
• W2556560417 date "2016-11-14" @default.
• W2556560417 modified "2023-10-18" @default.
• W2556560417 title "Structures of M₂(SO₂)₆B₁₂F₁₂ (M = Ag or K) and Ag₂(H₂O)₄B₁₂F₁₂: Comparison of the Coordination of SO₂ versus H₂O and of B₁₂F₁₂^2– versus Other Weakly Coordinating Anions to Metal Ions in the Solid State" @default.
• W2556560417 cites W111668754 @default.
• W2556560417 cites W1238428381 @default.
• W2556560417 cites W1524519604 @default.
• W2556560417 cites W1566662223 @default.
• W2556560417 cites W160026719 @default.
• W2556560417 cites W1972040576 @default.
• W2556560417 cites W1978607007 @default.
• W2556560417 cites W1990608474 @default.
• W2556560417 cites W1992054689 @default.
• W2556560417 cites W1998606004 @default.
• W2556560417 cites W2000293728 @default.
• W2556560417 cites W2003786461 @default.
• W2556560417 cites W2003893307 @default.
• W2556560417 cites W2008067460 @default.
• W2556560417 cites W2008847014 @default.
• W2556560417 cites W2012428667 @default.
• W2556560417 cites W2014416110 @default.
• W2556560417 cites W2016831704 @default.
• W2556560417 cites W2032664440 @default.
• W2556560417 cites W2034347538 @default.
• W2556560417 cites W2039987808 @default.
• W2556560417 cites W2049155665 @default.
• W2556560417 cites W2052489068 @default.
• W2556560417 cites W2054580951 @default.
• W2556560417 cites W2063372791 @default.
• W2556560417 cites W2064998085 @default.
• W2556560417 cites W2068803426 @default.
• W2556560417 cites W2074019256 @default.
• W2556560417 cites W2081857840 @default.
• W2556560417 cites W2087543000 @default.
• W2556560417 cites W2101741054 @default.
• W2556560417 cites W2105608313 @default.
• W2556560417 cites W2107332651 @default.
• W2556560417 cites W2126586781 @default.
• W2556560417 cites W2143066078 @default.
• W2556560417 cites W2151066710 @default.
• W2556560417 cites W2152902542 @default.
• W2556560417 cites W2160630041 @default.
• W2556560417 cites W2167590372 @default.
• W2556560417 cites W2199306156 @default.
• W2556560417 cites W2264164988 @default.
• W2556560417 cites W2413875421 @default.
• W2556560417 cites W2949252321 @default.
• W2556560417 cites W2951725030 @default.
• W2556560417 cites W2978367367 @default.
• W2556560417 cites W4301494119 @default.
• W2556560417 cites W2317911152 @default.
• W2556560417 doi "https://doi.org/10.1021/acs.inorgchem.6b01980" @default.
• W2556560417 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27934406" @default.
• W2556560417 hasPublicationYear "2016" @default.
• W2556560417 type Work @default.
• W2556560417 sameAs 2556560417 @default.
• W2556560417 citedByCount "22" @default.
• W2556560417 countsByYear W25565604172017 @default.
• W2556560417 countsByYear W25565604172018 @default.
• W2556560417 countsByYear W25565604172019 @default.
• W2556560417 countsByYear W25565604172020 @default.
• W2556560417 countsByYear W25565604172021 @default.
• W2556560417 countsByYear W25565604172022 @default.
• W2556560417 countsByYear W25565604172023 @default.
• W2556560417 crossrefType "journal-article" @default.
• W2556560417 hasAuthorship W2556560417A5012947921 @default.
• W2556560417 hasAuthorship W2556560417A5025788864 @default.
• W2556560417 hasAuthorship W2556560417A5028808065 @default.
• W2556560417 hasAuthorship W2556560417A5046928138 @default.
• W2556560417 hasAuthorship W2556560417A5083391134 @default.
• W2556560417 hasConcept C115624301 @default.
• W2556560417 hasConcept C145148216 @default.
• W2556560417 hasConcept C178790620 @default.
• W2556560417 hasConcept C183882617 @default.
• W2556560417 hasConcept C185592680 @default.
• W2556560417 hasConcept C194185919 @default.
• W2556560417 hasConcept C8010536 @default.
• W2556560417 hasConceptScore W2556560417C115624301 @default.
• W2556560417 hasConceptScore W2556560417C145148216 @default.
• W2556560417 hasConceptScore W2556560417C178790620 @default.
• W2556560417 hasConceptScore W2556560417C183882617 @default.
• W2556560417 hasConceptScore W2556560417C185592680 @default.
• W2556560417 hasConceptScore W2556560417C194185919 @default.
• W2556560417 hasConceptScore W2556560417C8010536 @default.
• W2556560417 hasFunder F4320309608 @default.
• W2556560417 hasFunder F4320320879 @default.
• W2556560417 hasFunder F4320338284 @default.
• W2556560417 hasFunder F4320338294 @default.
• W2556560417 hasIssue "23" @default.
• W2556560417 hasLocation W25565604171 @default.
• W2556560417 hasLocation W25565604172 @default.
• W2556560417 hasOpenAccess W2556560417 @default.

• next