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- W2556862714 abstract "Well‐defined magnetic polyelectrolytes with tetrachlorideferrate (FeCl 4 − ) as counter ion are prepared. In this approach, norbornene‐based monomer containing ammonium chloride group (TAENDI‐Cl) is designed and synthesized. Well‐defined magnetic polymers (Poly(TAENDI‐FeCl 4 )) are obtained by ring‐opening metathesis polymerization of TAENDI‐Cl in the presence of Grubbs third generation catalyst followed by complexing with FeCl 3 . Magnetic block copolymers are thus prepared. Both the monomer and polymers are paramagnetic as measured by superconducting quantum interference device method. Studies show that the magnetic susceptibility increases with increasing degree of polymerization (DP) and reaches maximum at DP of 100, and then decreases with increasing DP. Block copolymer with lower FeCl 4 − content shows higher magnetic susceptibility. And, by introducing FeCl 4 − , the polymers show obviously magnetic responsive in solution, powder, and film which have potential applications in magnetic switching, transport, and separation. image" @default.
- W2556862714 created "2016-11-30" @default.
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- W2556862714 date "2016-11-10" @default.
- W2556862714 modified "2023-10-06" @default.
- W2556862714 title "Well-Defined Magnetic Responsive Polymers Containing Ammonium FeCl<sub>4</sub>from ROMP" @default.
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- W2556862714 doi "https://doi.org/10.1002/macp.201600435" @default.
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