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• W2557015166 abstract "The silver(I) amidinates bis[μ- N 1 , N 2 -bis(propan-2-yl)benzamidinato-κ 2 N 1 : N 2 ]disilver(I), [Ag 2 (C 13 H 19 N 2 ) 2 ] or [Ag{PhC(N i Pr) 2 }] 2 ( 1 ), and bis(μ- N 1 , N 2 -dicyclohexyl-3-cyclopropylpropynamidinato-κ 2 N 1 : N 2 )disilver(I), [Ag 2 (C 18 H 27 N 2 ) 2 ] or [Ag{ cyclo -C 3 H 5 –C[triple-bond]C–C(NCy) 2 }] 2 ( 2a ), exist as centrosymmetric dimers with a planar Ag 2 N 4 C 2 ring and a common linear coordination of the metal atoms in the crystalline state. Moiety 2a forms a co-crystal with the related lithium amidinate, namely bis(μ- N 1 , N 2 -dicyclohexyl-3-cyclopropylpropynamidinato-κ 2 N 1 : N 2 )disilver(I) bis(μ- N 1 , N 2 -dicyclohexyl-3-cyclopropylpropynamidinato-κ 3 N 1 , N 2 : N 1 )bis(tetrahydrofuran-κ O )lithium(I) toluene monosolvate, [Ag 2 (C 18 H 27 N 2 ) 2 ][Li 2 (C 18 H 27 N 2 ) 2 (C 4 H 8 O) 2 ]·C 7 H 8 or [Ag{ cyclo -C 3 H 5 –C[triple-bond] C – C (NCy) 2 }] 2 [Li{ cyclo -C 3 H 5 –C[triple-bond]C–C(NCy) 2 }(THF)] 2 ·C 7 H 8 , composed as 2a × 2b × toluene. The lithium moiety 2b features a typical ladder-type dimeric structure with a distorted tetrahedral coordination of the metal atoms. In the silver(I) derivatives 1 and 2a , the amidinate ligand adopts a μ-κ N :κ N ′ coordination, while it is a μ-κ N :κ N :κ N ′-coordination in the case of lithium derivative 2b ." @default.
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• W2557015166 date "2016-11-15" @default.
• W2557015166 modified "2023-09-24" @default.
• W2557015166 title "Crystal and molecular structures of two silver(I) amidinates, including an unexpected co-crystal with a lithium amidinate" @default.
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• W2557015166 doi "https://doi.org/10.1107/s2056989016017680" @default.
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