FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2557284494> ?p ?o ?g. }

• W2557284494 endingPage "12862" @default.
• W2557284494 startingPage "12850" @default.
• W2557284494 abstract "Recently, the addition of negatively charged liposomes was shown to increase the quantum yield of the photocatalytic reduction of 5,5'-dithio(2-nitrobenzoic acid) (H2DTNB) to 2-nitro-5-thiobenzoic acid (H2NTB) by triethanolamine using meso-tetra(4-(N-methylpyridinium)porphyrinato zinc chloride as photosensitizer. In this work, we investigate in detail the kinetics of this photocatalytic reaction both in homogeneous solution and at the surface of negatively charged liposomes, to unravel the effects of liposomes on the mechanism of the photoreaction. In homogeneous solution, the reaction is initiated by oxidative quenching. Both static (singlet) and dynamic (triplet) quenching of the photosensitizer contribute to the formation of the photoproduct. In these conditions, the reaction is limited by the low efficiency of reductive regeneration of the photosensitizer, compared to charge recombination. Upon adsorption of the positively charged photosensitizer to the negative surface of the liposomes, however, both static and dynamic oxidative quenching become ineffective due to electrostatic repulsion of the dianionic DTNB2- from the negatively charged membrane. In such conditions, photoreduction occurs via reductive quenching, showing that the addition of liposomes can truly modify the mechanism of photocatalyzed redox reactions." @default.
• W2557284494 created "2016-12-08" @default.
• W2557284494 creator A5022426796 @default.
• W2557284494 creator A5056968669 @default.
• W2557284494 creator A5058318761 @default.
• W2557284494 creator A5075602502 @default.
• W2557284494 creator A5085988375 @default.
• W2557284494 date "2016-12-12" @default.
• W2557284494 modified "2023-09-25" @default.
• W2557284494 title "The Effect of Liposomes on the Kinetics and Mechanism of the Photocatalytic Reduction of 5,5′-Dithiobis(2-Nitrobenzoic Acid) by Triethanolamine" @default.
• W2557284494 cites W1661851364 @default.
• W2557284494 cites W1965296958 @default.
• W2557284494 cites W1971113415 @default.
• W2557284494 cites W1976025388 @default.
• W2557284494 cites W1979376507 @default.
• W2557284494 cites W1981567239 @default.
• W2557284494 cites W1987067484 @default.
• W2557284494 cites W1991284957 @default.
• W2557284494 cites W1992464644 @default.
• W2557284494 cites W1993473788 @default.
• W2557284494 cites W2005206480 @default.
• W2557284494 cites W2006883146 @default.
• W2557284494 cites W2009925915 @default.
• W2557284494 cites W2010223358 @default.
• W2557284494 cites W2010333303 @default.
• W2557284494 cites W2020985880 @default.
• W2557284494 cites W2023181936 @default.
• W2557284494 cites W2026773863 @default.
• W2557284494 cites W2032388678 @default.
• W2557284494 cites W2041294529 @default.
• W2557284494 cites W2041323474 @default.
• W2557284494 cites W2046295231 @default.
• W2557284494 cites W2046426008 @default.
• W2557284494 cites W2046537181 @default.
• W2557284494 cites W2073417483 @default.
• W2557284494 cites W2076547331 @default.
• W2557284494 cites W2079465278 @default.
• W2557284494 cites W2086007950 @default.
• W2557284494 cites W2086736597 @default.
• W2557284494 cites W2092212581 @default.
• W2557284494 cites W2093157330 @default.
• W2557284494 cites W2098205015 @default.
• W2557284494 cites W2098661937 @default.
• W2557284494 cites W2110357670 @default.
• W2557284494 cites W2119558385 @default.
• W2557284494 cites W2147536016 @default.
• W2557284494 cites W2154141463 @default.
• W2557284494 cites W2158833995 @default.
• W2557284494 cites W2160316077 @default.
• W2557284494 cites W2162272842 @default.
• W2557284494 cites W2950049292 @default.
• W2557284494 cites W2950139251 @default.
• W2557284494 cites W4301332574 @default.
• W2557284494 doi "https://doi.org/10.1021/acs.jpcb.6b09635" @default.
• W2557284494 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27936697" @default.
• W2557284494 hasPublicationYear "2016" @default.
• W2557284494 type Work @default.
• W2557284494 sameAs 2557284494 @default.
• W2557284494 citedByCount "5" @default.
• W2557284494 countsByYear W25572844942016 @default.
• W2557284494 countsByYear W25572844942018 @default.
• W2557284494 countsByYear W25572844942022 @default.
• W2557284494 crossrefType "journal-article" @default.
• W2557284494 hasAuthorship W2557284494A5022426796 @default.
• W2557284494 hasAuthorship W2557284494A5056968669 @default.
• W2557284494 hasAuthorship W2557284494A5058318761 @default.
• W2557284494 hasAuthorship W2557284494A5075602502 @default.
• W2557284494 hasAuthorship W2557284494A5085988375 @default.
• W2557284494 hasConcept C113196181 @default.
• W2557284494 hasConcept C121332964 @default.
• W2557284494 hasConcept C121745418 @default.
• W2557284494 hasConcept C148898269 @default.
• W2557284494 hasConcept C161790260 @default.
• W2557284494 hasConcept C171001562 @default.
• W2557284494 hasConcept C178790620 @default.
• W2557284494 hasConcept C185154212 @default.
• W2557284494 hasConcept C185592680 @default.
• W2557284494 hasConcept C2775897365 @default.
• W2557284494 hasConcept C2777516457 @default.
• W2557284494 hasConcept C2781469039 @default.
• W2557284494 hasConcept C540031477 @default.
• W2557284494 hasConcept C55493867 @default.
• W2557284494 hasConcept C62520636 @default.
• W2557284494 hasConcept C65165184 @default.
• W2557284494 hasConcept C75473681 @default.
• W2557284494 hasConcept C91881484 @default.
• W2557284494 hasConceptScore W2557284494C113196181 @default.
• W2557284494 hasConceptScore W2557284494C121332964 @default.
• W2557284494 hasConceptScore W2557284494C121745418 @default.
• W2557284494 hasConceptScore W2557284494C148898269 @default.
• W2557284494 hasConceptScore W2557284494C161790260 @default.
• W2557284494 hasConceptScore W2557284494C171001562 @default.
• W2557284494 hasConceptScore W2557284494C178790620 @default.
• W2557284494 hasConceptScore W2557284494C185154212 @default.
• W2557284494 hasConceptScore W2557284494C185592680 @default.
• W2557284494 hasConceptScore W2557284494C2775897365 @default.
• W2557284494 hasConceptScore W2557284494C2777516457 @default.
• W2557284494 hasConceptScore W2557284494C2781469039 @default.

• next