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- W2557363469 abstract "The Glaser-Hay coupling of terminal alkynes is a useful synthetic reaction for the preparation of polyynes; however, chemoselectivity issues have precluded its widespread utilization. Conducting the reaction on a solid-support provides a mechanism to alleviate the chemoselectivity issues and provide products in high purities and yields. Moreover, the polyyne core is a key component to several natural products. Herein, we describe the application of a solid-supported Glaser-Hay reaction in the preparation of several natural products. These compounds were then screened for antibacterial activity, illustrating the utility of the methodology." @default.
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- W2557363469 date "2016-12-07" @default.
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- W2557363469 title "Application of the Solid-Supported Glaser–Hay Reaction to Natural Product Synthesis" @default.
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- W2557363469 doi "https://doi.org/10.1021/acs.joc.6b02407" @default.
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