FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2557563809> ?p ?o ?g. }

• W2557563809 endingPage "31" @default.
• W2557563809 startingPage "23" @default.
• W2557563809 abstract "The system of intermolecular interactions is very similar in the solid state of the chiral and racemic α-methoxyphenylacetic acids (α-MPAA) indicated by both Differential Scanning Calorimetry (DSC) and FTIR-spectroscopy, and even proved by single crystal structure determination. It makes the resolution of such a racemate compound challenging even by supercritical fluid extraction. The chiral (S)-α-methoxyphenylacetic acid (1) crystallizes in orthorhombic crystal system (space group P212121, a = 6.8795(3) Å, b = 7.0124(3) Å, c = 17.4578(8) Å, Z = 4, R = 0.0373), while its 1:1 salt formed with (S)-1-cyclohexylethyl amine (3) is found to be monoclinic (s.g. P21, a = 9.5290(12) Å, b = 6.5909(10) Å, c = 13.869(2) Å, β = 103.13(3)°, Z = 2, R = 0.0477). The packing arrangement in the (S)-(S) ammonium carboxylate type salt is columnar. The columns are hydrophylic inward and hydrophobic outward, that results in fibrous growth of the salt crystals melting at 163 °C. The crystal habit of the higher melting diastereomeric (S)-(R) salt (mp. 187 °C) is also fibrous, its structure is closely related to the (S)-(S)-salt by the similarities observed in their IR spectra. The DSC and powder XRD studies on the chiral and racemic acids, and on the pair of diastereomeric salts helped us to construct and calculate the binary and ternary phase diagrams of the system components, including their eutectic temperatures and compositions, as well." @default.
• W2557563809 created "2016-12-08" @default.
• W2557563809 creator A5024187854 @default.
• W2557563809 creator A5035362527 @default.
• W2557563809 creator A5036348715 @default.
• W2557563809 creator A5056198233 @default.
• W2557563809 creator A5072000259 @default.
• W2557563809 date "2017-02-01" @default.
• W2557563809 modified "2023-10-08" @default.
• W2557563809 title "Structural, analytical and DSC references to resolution of 2-methoxy-2-phenylacetic acid with chiral 1-cyclohexylethylamines through gas-antisolvent precipitation" @default.
• W2557563809 cites W1968567168 @default.
• W2557563809 cites W1971713250 @default.
• W2557563809 cites W1973139373 @default.
• W2557563809 cites W1977186893 @default.
• W2557563809 cites W1994498372 @default.
• W2557563809 cites W2009032936 @default.
• W2557563809 cites W2009866404 @default.
• W2557563809 cites W2023657736 @default.
• W2557563809 cites W2026838519 @default.
• W2557563809 cites W2031422128 @default.
• W2557563809 cites W2032842297 @default.
• W2557563809 cites W2050582435 @default.
• W2557563809 cites W2057070159 @default.
• W2557563809 cites W2057886780 @default.
• W2557563809 cites W2062929547 @default.
• W2557563809 cites W2074330907 @default.
• W2557563809 cites W2082473798 @default.
• W2557563809 cites W2082863831 @default.
• W2557563809 cites W2086945873 @default.
• W2557563809 cites W2090804568 @default.
• W2557563809 cites W2094399616 @default.
• W2557563809 cites W2107668378 @default.
• W2557563809 cites W2128179591 @default.
• W2557563809 cites W2129039800 @default.
• W2557563809 cites W2131350133 @default.
• W2557563809 cites W2135052904 @default.
• W2557563809 cites W2166689829 @default.
• W2557563809 cites W2169378159 @default.
• W2557563809 cites W2264883586 @default.
• W2557563809 cites W2949845335 @default.
• W2557563809 cites W4211053799 @default.
• W2557563809 doi "https://doi.org/10.1016/j.tca.2016.11.017" @default.
• W2557563809 hasPublicationYear "2017" @default.
• W2557563809 type Work @default.
• W2557563809 sameAs 2557563809 @default.
• W2557563809 citedByCount "3" @default.
• W2557563809 countsByYear W25575638092021 @default.
• W2557563809 countsByYear W25575638092022 @default.
• W2557563809 crossrefType "journal-article" @default.
• W2557563809 hasAuthorship W2557563809A5024187854 @default.
• W2557563809 hasAuthorship W2557563809A5035362527 @default.
• W2557563809 hasAuthorship W2557563809A5036348715 @default.
• W2557563809 hasAuthorship W2557563809A5056198233 @default.
• W2557563809 hasAuthorship W2557563809A5072000259 @default.
• W2557563809 hasBestOaLocation W25575638092 @default.
• W2557563809 hasConcept C112887158 @default.
• W2557563809 hasConcept C115624301 @default.
• W2557563809 hasConcept C121332964 @default.
• W2557563809 hasConcept C138716334 @default.
• W2557563809 hasConcept C156217769 @default.
• W2557563809 hasConcept C178790620 @default.
• W2557563809 hasConcept C18168003 @default.
• W2557563809 hasConcept C185592680 @default.
• W2557563809 hasConcept C192562407 @default.
• W2557563809 hasConcept C203036418 @default.
• W2557563809 hasConcept C2778074193 @default.
• W2557563809 hasConcept C2781219336 @default.
• W2557563809 hasConcept C32909587 @default.
• W2557563809 hasConcept C37243968 @default.
• W2557563809 hasConcept C39519442 @default.
• W2557563809 hasConcept C486523 @default.
• W2557563809 hasConcept C61276311 @default.
• W2557563809 hasConcept C71240020 @default.
• W2557563809 hasConcept C79191725 @default.
• W2557563809 hasConcept C8010536 @default.
• W2557563809 hasConcept C87976508 @default.
• W2557563809 hasConcept C97355855 @default.
• W2557563809 hasConceptScore W2557563809C112887158 @default.
• W2557563809 hasConceptScore W2557563809C115624301 @default.
• W2557563809 hasConceptScore W2557563809C121332964 @default.
• W2557563809 hasConceptScore W2557563809C138716334 @default.
• W2557563809 hasConceptScore W2557563809C156217769 @default.
• W2557563809 hasConceptScore W2557563809C178790620 @default.
• W2557563809 hasConceptScore W2557563809C18168003 @default.
• W2557563809 hasConceptScore W2557563809C185592680 @default.
• W2557563809 hasConceptScore W2557563809C192562407 @default.
• W2557563809 hasConceptScore W2557563809C203036418 @default.
• W2557563809 hasConceptScore W2557563809C2778074193 @default.
• W2557563809 hasConceptScore W2557563809C2781219336 @default.
• W2557563809 hasConceptScore W2557563809C32909587 @default.
• W2557563809 hasConceptScore W2557563809C37243968 @default.
• W2557563809 hasConceptScore W2557563809C39519442 @default.
• W2557563809 hasConceptScore W2557563809C486523 @default.
• W2557563809 hasConceptScore W2557563809C61276311 @default.
• W2557563809 hasConceptScore W2557563809C71240020 @default.
• W2557563809 hasConceptScore W2557563809C79191725 @default.
• W2557563809 hasConceptScore W2557563809C8010536 @default.
• W2557563809 hasConceptScore W2557563809C87976508 @default.

• next