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- W2558082002 abstract "A novel, base-catalyzed and highly diastereoselective direct Michael addition-isomerization sequence is presented for the efficient synthesis of Rauhut–Currier-type adducts. An unexpected α-addition of γ-butyrolactam onto the 3-acyl coumarin derivatives was observed rather than the γ-addition, which is more common. The adducts could further undergo hydrolysis/decarboxylation to generate the products which are equivalent to those obtained by α-addition of γ-butyrolactam onto the corresponding chalcones." @default.
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- W2558082002 date "2016-12-12" @default.
- W2558082002 modified "2023-10-14" @default.
- W2558082002 title "Diastereoselective Synthesis of Rauhut–Currier-Type Adducts via an Unexpected α-Addition of α,β-Unsaturated γ-Butyrolactams to Coumarin Derivatives" @default.
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- W2558082002 doi "https://doi.org/10.1021/acs.joc.6b02526" @default.
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