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• W2558714181 abstract "Abstract A series of (90– x )Li 2 B 4 O 7 -10Nb 2 O 5 - x Nd 2 O 3 glass samples ( x =0, 5 mol.%, 10 mol.%, 15 mol.%, 20 mol.% and 25 mol.%) were synthesized using melt quenching technique. X-ray diffraction (XRD), differential thermal analyzer (DTA), Fourier transformed infrared (FTIR), ultraviolet-visible-near-infrared (UV-Vis-NIR) spectrometer and photoluminescence (PL) spectroscopic characterizations were made to examine the influence of Nd 3+ concentration on the physical, structural and optical properties. Various physical properties such as glasses density, molar volume, thermal stability, ion concentration, polar on radius, inter-nuclear distance, field strength, cut-off wavelength, energy band gap and Urbach energy were calculated. The samples were amorphous in nature and confirmed from XRD pattern. The FTIR spectra revealed the presence of BO 3 and BO 4 functional groups. UV-Vis-NIR spectra exhibited nine prominent bands centered at 353, 430, 475, 524, 583, 681, 745, 803, 875 nm corresponding to the transitions from the ground state to 4 D 3/2 , 2 P 1/2 , 2 G 9/2 , 4 G 7/2 , 4 G 5/2 , 4 F 9/2 , 4 F 7/2 , 4 F 5/2 , 4 F 3/2 excited states, respectively. Moreover, the emission spectra at 355 nm excitation displayed three peaks centered at 903 nm ( 4 F 3/2 → 4 I 9/2 ), 1059 nm ( 4 F 3/2 → 4 I 11/2 ) and 1333 nm ( 4 F 3/2 → 4 I 13/2 ), respectively. Fluorescence lifetime was recorded between 53.69 to 28.43 µs. It was found that varying concentration of Nd 3+ ions strongly affected the physical, structural and optical properties of the glass samples." @default.
• W2558714181 created "2016-12-08" @default.
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• W2558714181 date "2016-12-01" @default.
• W2558714181 modified "2023-10-16" @default.
• W2558714181 title "Synthesis and characterization of lithium niobium borate glasses containing neodymium" @default.
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• W2558714181 doi "https://doi.org/10.1016/s1002-0721(16)60154-0" @default.
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