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- W2558822712 endingPage "259" @default.
- W2558822712 startingPage "254" @default.
- W2558822712 abstract "The emission process of the o-carborane dyad with anthracene originating from the twisted intramolecular charge transfer (TICT) state in the crystalline state is described. The anthracene-o-carborane dyad was synthesized and its optical properties were investigated. Initially, the dyad had aggregation- and crystallization-induced emission enhancement (AIEE and CIEE) properties via the intramolecular charge transfer (ICT) state. Interestingly, the dyad presented the dual-emissions assigned to both locally excited (LE) and ICT states in solution. From the mechanistic studies and computer calculations, it was indicated that the emission band from the ICT should be attributable to the TICT emission. Surprisingly, even in the crystalline state, the TICT emission was observed. It was proposed from that the compact sphere shape of o-carborane would allow for rotation even in the condensed state." @default.
- W2558822712 created "2016-12-08" @default.
- W2558822712 creator A5001173964 @default.
- W2558822712 creator A5023671279 @default.
- W2558822712 creator A5036531859 @default.
- W2558822712 creator A5043396344 @default.
- W2558822712 creator A5073553496 @default.
- W2558822712 date "2016-12-01" @default.
- W2558822712 modified "2023-10-14" @default.
- W2558822712 title "Solid‐State Emission of the Anthracene‐<i>o</i>‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State" @default.
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