Matches in SemOpenAlex for { <https://semopenalex.org/work/W2558888948> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2558888948 endingPage "C621" @default.
- W2558888948 startingPage "C621" @default.
- W2558888948 abstract "Small molecules, such as urea, thiourea, perhydrotriphenylene can be co-crystallised with long-chain hydrocarbon molecules to form inclusion compounds. The guest chains are confined to narrow, approximately cylindrical, channels created by the host small-molecule lattice. The stoichiometry and the conformations of the chains included inside the channels are function of internal interactions such as intra-chain interaction, but also of overall co-operative properties of the resulting three dimensionally ordered single crystal. These intergrowth compounds may form incommensurate composite crystals. A prototype example of such uniaxial intergrowth aperiodic crystals is n-alkane (CnH2n+2)/urea (CO(NH2)2). In these supra-molecular systems, urea molecules are connected by H-bonds and form helical ribbons, which repeat every six urea molecules to form a series of linear, hexagonal tunnels that can accommodate linear alkanes. Because the channels (~0.53 nm) are larger than the hydrocarbon chains, guests are held loosely and can undergo substantial motions. A significant amount of diffuse scattering of the first and second kinds can be depicted in scattering experiments, static or dynamic. These materials undergo a large variety of continuous or weakly first order structural phase transitions when changing the alkane molecule length and giving place to large pre-transitional effects. The talk will give an overview of the diffuse scattering in these compounds and will focus on connection with aperiodicity." @default.
- W2558888948 created "2016-12-08" @default.
- W2558888948 creator A5013767185 @default.
- W2558888948 creator A5020989101 @default.
- W2558888948 creator A5042669825 @default.
- W2558888948 creator A5076991030 @default.
- W2558888948 creator A5089185306 @default.
- W2558888948 date "2014-08-05" @default.
- W2558888948 modified "2023-10-18" @default.
- W2558888948 title "Diffuse scattering and phase transitions in aperiodic inclusion compounds" @default.
- W2558888948 doi "https://doi.org/10.1107/s2053273314093784" @default.
- W2558888948 hasPublicationYear "2014" @default.
- W2558888948 type Work @default.
- W2558888948 sameAs 2558888948 @default.
- W2558888948 citedByCount "0" @default.
- W2558888948 crossrefType "journal-article" @default.
- W2558888948 hasAuthorship W2558888948A5013767185 @default.
- W2558888948 hasAuthorship W2558888948A5020989101 @default.
- W2558888948 hasAuthorship W2558888948A5042669825 @default.
- W2558888948 hasAuthorship W2558888948A5076991030 @default.
- W2558888948 hasAuthorship W2558888948A5089185306 @default.
- W2558888948 hasBestOaLocation W25588889481 @default.
- W2558888948 hasConcept C104247578 @default.
- W2558888948 hasConcept C114614502 @default.
- W2558888948 hasConcept C115624301 @default.
- W2558888948 hasConcept C120665830 @default.
- W2558888948 hasConcept C121332964 @default.
- W2558888948 hasConcept C159467904 @default.
- W2558888948 hasConcept C178790620 @default.
- W2558888948 hasConcept C185592680 @default.
- W2558888948 hasConcept C191486275 @default.
- W2558888948 hasConcept C192562407 @default.
- W2558888948 hasConcept C24890656 @default.
- W2558888948 hasConcept C2780538656 @default.
- W2558888948 hasConcept C2781204021 @default.
- W2558888948 hasConcept C32909587 @default.
- W2558888948 hasConcept C33923547 @default.
- W2558888948 hasConcept C44280652 @default.
- W2558888948 hasConcept C8010536 @default.
- W2558888948 hasConceptScore W2558888948C104247578 @default.
- W2558888948 hasConceptScore W2558888948C114614502 @default.
- W2558888948 hasConceptScore W2558888948C115624301 @default.
- W2558888948 hasConceptScore W2558888948C120665830 @default.
- W2558888948 hasConceptScore W2558888948C121332964 @default.
- W2558888948 hasConceptScore W2558888948C159467904 @default.
- W2558888948 hasConceptScore W2558888948C178790620 @default.
- W2558888948 hasConceptScore W2558888948C185592680 @default.
- W2558888948 hasConceptScore W2558888948C191486275 @default.
- W2558888948 hasConceptScore W2558888948C192562407 @default.
- W2558888948 hasConceptScore W2558888948C24890656 @default.
- W2558888948 hasConceptScore W2558888948C2780538656 @default.
- W2558888948 hasConceptScore W2558888948C2781204021 @default.
- W2558888948 hasConceptScore W2558888948C32909587 @default.
- W2558888948 hasConceptScore W2558888948C33923547 @default.
- W2558888948 hasConceptScore W2558888948C44280652 @default.
- W2558888948 hasConceptScore W2558888948C8010536 @default.
- W2558888948 hasIssue "a1" @default.
- W2558888948 hasLocation W25588889481 @default.
- W2558888948 hasOpenAccess W2558888948 @default.
- W2558888948 hasPrimaryLocation W25588889481 @default.
- W2558888948 hasRelatedWork W1593068886 @default.
- W2558888948 hasRelatedWork W2012345717 @default.
- W2558888948 hasRelatedWork W2075817299 @default.
- W2558888948 hasRelatedWork W2329996275 @default.
- W2558888948 hasRelatedWork W2368204824 @default.
- W2558888948 hasRelatedWork W2463657710 @default.
- W2558888948 hasRelatedWork W2767205953 @default.
- W2558888948 hasRelatedWork W2942835415 @default.
- W2558888948 hasRelatedWork W4214913594 @default.
- W2558888948 hasRelatedWork W2531233335 @default.
- W2558888948 hasVolume "70" @default.
- W2558888948 isParatext "false" @default.
- W2558888948 isRetracted "false" @default.
- W2558888948 magId "2558888948" @default.
- W2558888948 workType "article" @default.