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- W2559897908 abstract "Abstract The reaction kinetics of carbon dioxide and sodium hydroxide (nominally 0.1 N and 0.3 N) in aqueous glycerol were measured in a wetted wall column (WWC) at 20, 30, and 40 °C. Glycerol was added at 0–89 wt% to achieve a liquid viscosity ( μ L ) of 0.89–65 cP. Compared to pure aqueous alkaline solution, the absorption rate ( k g ′) initially increased by 30% and then decreased rapidly by 75% with increasing glycerol. Based on the measured k g ′, a model was developed to calculate the overall reaction rate constant ( k Alk ), which resulted from the competing effects of CO 2 /NaOH ( k OH - ) and CO 2 /glyceroxide ( k Glycerol - ) reactions. The k Glycerol - was 6–7 times faster than k OH - . The non-monotonic trend of k g ′ was the combined effect of k Alk increasing and diffusivity ( D CO2 ) decreasing when glycerol increased. The effect of alkalinity depletion at the gas/liquid interface has been included in the kinetic model. The average depletion for 0.1 N NaOH is 4% for water and 20% for 89 wt% glycerol. Average depletion was less than 3% for 0.3 N NaOH. The addition of 0.05 N sodium carbonate has an insignificant effect on k g ′." @default.
- W2559897908 created "2016-12-16" @default.
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- W2559897908 date "2017-04-01" @default.
- W2559897908 modified "2023-09-28" @default.
- W2559897908 title "Reaction kinetics of carbon dioxide and hydroxide in aqueous glycerol" @default.
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- W2559897908 doi "https://doi.org/10.1016/j.ces.2016.11.048" @default.
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