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- W2559898413 abstract "Resveratrol-based natural products constitute a valuable source of unique compounds with diverse biological activities. In this report we investigate demethylation strategies to minimize formation of cyclized and dimerized products during the synthesis of viniferifuran and analogues. We found that boron trichloride/tetra-n-butylammonium iodide (BCl3/TBAI) is typically more effective than boron tribromide (BBr3). Based on these findings we carried out the first syntheses of dehydro-δ-viniferin, resveratrol-piceatannol hybrid and anigopreissin A. In addition, we have developed a short and efficient route to viniferifuran that was obtained in 13% yield over six steps." @default.
- W2559898413 created "2016-12-16" @default.
- W2559898413 creator A5063973812 @default.
- W2559898413 creator A5072343210 @default.
- W2559898413 date "2016-12-08" @default.
- W2559898413 modified "2023-09-26" @default.
- W2559898413 title "Total Synthesis of Viniferifuran, Resveratrol-Piceatannol Hybrid, Anigopreissin A and Analogues - Investigation of Demethylation Strategies" @default.
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- W2559898413 doi "https://doi.org/10.1002/adsc.201601089" @default.
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