Matches in SemOpenAlex for { <https://semopenalex.org/work/W2559934293> ?p ?o ?g. }
- W2559934293 endingPage "437" @default.
- W2559934293 startingPage "433" @default.
- W2559934293 abstract "To date, cleavage of the C−N bond in aromatic amides has been achieved in molecules with a distorted constitutional framework around the nitrogen atom. In this report, a nickel-catalyzed reduction of planar amides to the corresponding lower hydrocarbon homologue has been reported. This involves a one-pot reductive cleavage of the C−N bond followed by a tandem C−CO bond break in the presence of a hydride source. Substrate scope circumscribes deamidation examples which proceed via oxidative addition of nickel in the amide bonds of nontwisted amides. Mechanistic studies involving isolation and characterization of involved intermediates via different spectroscopic techniques reveal a deeper introspection into the plausible catalytic cycle for the methodology." @default.
- W2559934293 created "2016-12-16" @default.
- W2559934293 creator A5003051659 @default.
- W2559934293 creator A5012345512 @default.
- W2559934293 creator A5015993039 @default.
- W2559934293 creator A5051885484 @default.
- W2559934293 creator A5062826786 @default.
- W2559934293 date "2016-12-13" @default.
- W2559934293 modified "2023-09-29" @default.
- W2559934293 title "Nickel-Catalyzed Deamidative Step-Down Reduction of Amides to Aromatic Hydrocarbons" @default.
- W2559934293 cites W1159743676 @default.
- W2559934293 cites W1877160790 @default.
- W2559934293 cites W1929109117 @default.
- W2559934293 cites W1943008936 @default.
- W2559934293 cites W1963815550 @default.
- W2559934293 cites W1968294999 @default.
- W2559934293 cites W1970813681 @default.
- W2559934293 cites W1970866898 @default.
- W2559934293 cites W1974627875 @default.
- W2559934293 cites W1979545752 @default.
- W2559934293 cites W1985066293 @default.
- W2559934293 cites W1988533616 @default.
- W2559934293 cites W1988794984 @default.
- W2559934293 cites W1991971314 @default.
- W2559934293 cites W1993233047 @default.
- W2559934293 cites W2001868581 @default.
- W2559934293 cites W2004462410 @default.
- W2559934293 cites W2009463098 @default.
- W2559934293 cites W2016666999 @default.
- W2559934293 cites W2024983608 @default.
- W2559934293 cites W2032731092 @default.
- W2559934293 cites W2040270294 @default.
- W2559934293 cites W2046375331 @default.
- W2559934293 cites W2051760313 @default.
- W2559934293 cites W2072102128 @default.
- W2559934293 cites W2080691320 @default.
- W2559934293 cites W2085516317 @default.
- W2559934293 cites W2085559348 @default.
- W2559934293 cites W2086989143 @default.
- W2559934293 cites W2094640281 @default.
- W2559934293 cites W2094871139 @default.
- W2559934293 cites W2099035387 @default.
- W2559934293 cites W2102141271 @default.
- W2559934293 cites W2104884894 @default.
- W2559934293 cites W2111494179 @default.
- W2559934293 cites W2115438289 @default.
- W2559934293 cites W2119158627 @default.
- W2559934293 cites W2132761118 @default.
- W2559934293 cites W2135346135 @default.
- W2559934293 cites W2147309877 @default.
- W2559934293 cites W2237104335 @default.
- W2559934293 cites W2257114829 @default.
- W2559934293 cites W2263756718 @default.
- W2559934293 cites W2271858140 @default.
- W2559934293 cites W2281650513 @default.
- W2559934293 cites W2307580311 @default.
- W2559934293 cites W2316071128 @default.
- W2559934293 cites W2318478040 @default.
- W2559934293 cites W2325521630 @default.
- W2559934293 cites W2328044246 @default.
- W2559934293 cites W2331129062 @default.
- W2559934293 cites W2338100037 @default.
- W2559934293 cites W2341379833 @default.
- W2559934293 cites W2398305159 @default.
- W2559934293 cites W2529166689 @default.
- W2559934293 cites W2529598762 @default.
- W2559934293 cites W2953359068 @default.
- W2559934293 cites W3004816419 @default.
- W2559934293 cites W4247409343 @default.
- W2559934293 cites W4362224113 @default.
- W2559934293 doi "https://doi.org/10.1021/acscatal.6b03040" @default.
- W2559934293 hasPublicationYear "2016" @default.
- W2559934293 type Work @default.
- W2559934293 sameAs 2559934293 @default.
- W2559934293 citedByCount "89" @default.
- W2559934293 countsByYear W25599342932017 @default.
- W2559934293 countsByYear W25599342932018 @default.
- W2559934293 countsByYear W25599342932019 @default.
- W2559934293 countsByYear W25599342932020 @default.
- W2559934293 countsByYear W25599342932021 @default.
- W2559934293 countsByYear W25599342932022 @default.
- W2559934293 countsByYear W25599342932023 @default.
- W2559934293 crossrefType "journal-article" @default.
- W2559934293 hasAuthorship W2559934293A5003051659 @default.
- W2559934293 hasAuthorship W2559934293A5012345512 @default.
- W2559934293 hasAuthorship W2559934293A5015993039 @default.
- W2559934293 hasAuthorship W2559934293A5051885484 @default.
- W2559934293 hasAuthorship W2559934293A5062826786 @default.
- W2559934293 hasConcept C161790260 @default.
- W2559934293 hasConcept C178790620 @default.
- W2559934293 hasConcept C185592680 @default.
- W2559934293 hasConcept C21951064 @default.
- W2559934293 hasConcept C2777961443 @default.
- W2559934293 hasConcept C2778439535 @default.
- W2559934293 hasConcept C3044715 @default.
- W2559934293 hasConcept C32909587 @default.
- W2559934293 hasConcept C504270822 @default.
- W2559934293 hasConcept C512968161 @default.