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• W2560146611 abstract "Abstract Simple, accurate and high-throughput pretreatment method would facilitate large-scale studies of trace analysis in complex samples. Magnetic mixed hemimicelles solid-phase extraction has the power to become a key pretreatment method in biological, environmental and clinical research. However, lacking of experimental predictability and unsharpness of extraction mechanism limit the development of this promising method. Herein, this work tries to establish theoretical-based experimental designs for extraction of trace analytes from complex samples using magnetic mixed hemimicelles solid-phase extraction. We selected three categories and six sub-types of compounds for systematic comparative study of extraction mechanism, and comprehensively illustrated the roles of different force (hydrophobic interaction, π-π stacking interactions, hydrogen-bonding interaction, electrostatic interaction) for the first time. What’s more, the application guidelines for supporting materials, surfactants and sample matrix were also summarized. The extraction mechanism and platform established in the study render its future promising for foreseeable and efficient pretreatment under theoretical based experimental design for trace analytes from environmental, biological and clinical samples." @default.
• W2560146611 created "2016-12-16" @default.
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• W2560146611 date "2016-12-07" @default.
• W2560146611 modified "2023-10-14" @default.
• W2560146611 title "Platform construction and extraction mechanism study of magnetic mixed hemimicelles solid-phase extraction" @default.
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• W2560146611 doi "https://doi.org/10.1038/srep38106" @default.
• W2560146611 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5141489" @default.
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