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• W2560149846 abstract "In this study, we report the curing of ESO with biobased dicarboxylic acids (DCAs) with different carbon chain-lengths to synthesize fully sustainable polymers. Both non-isothermal and isothermal curing processes analysis indicated that the curing rate and activation energy decreased with increasing chain-length of DCAs. The optimum COOH/epoxy molar ratio is 0.7 for preparation of ESO/DCA cured product with maximum degree of crosslinking. Addition of 4-N, N-dimethylaminopyridine (DMAP) as a catalyst can efficiently accelerate the curing rate and reduce activation energy. We systemtically studied the effect of chain-length of DCAs on the physical properties of cured products, and found that with increase in chain-length of DCAs, the glass transition temperature of the cured ESO/DCA decreased, the tensile strength and Young's modulus increased while elongation at break decreased, due to the decreased crosslinking density resulted from the increased chain-length between crosslinking sites. All cured ESO/DCA showed excellent thermal stability with initial decomposition temperature of higher than 340 °C." @default.
• W2560149846 created "2016-12-16" @default.
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• W2560149846 date "2017-02-01" @default.
• W2560149846 modified "2023-10-12" @default.
• W2560149846 title "Curing behavior of epoxidized soybean oil with biobased dicarboxylic acids" @default.
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• W2560149846 doi "https://doi.org/10.1016/j.polymertesting.2016.12.007" @default.
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