FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2560204602> ?p ?o ?g. }

• W2560204602 endingPage "12843" @default.
• W2560204602 startingPage "12832" @default.
• W2560204602 abstract "The article describes one-pot synthesis and structural elucidation of tc-[RuII(pap)2(L•–)]ClO4 [1]ClO4 and tc-[RuII(pap)2(L′–)]ClO4 [2]ClO4, which were obtained from tc-[RuII(pap)2(EtOH)2](ClO4)2 and benzofuroxan (L = 1,2-dinitrosobenzene, an intermediate tautomeric form of the biologically active benzofuroxan, L′– = 2-nitrosoanilido, pap = 2-phenylazopyridine, tc = trans and cis corresponding to pyridine and azo nitrogen donors of pap, respectively). The same reaction with the newly synthesized and structurally characterized metal precursor cc-RuII(2,6-dichloropap)2Cl2, however, affords isomeric ct-[RuII(2,6-dichloropap)2(L•–)]+ (3a+) and tc-[RuII(2,6-dichloropap)2(L•–)]+ (3b+) (cc, ct, and tc with respect to pyridine and azo nitrogens of 2,6-dichloropap) with the structural authentication of elusive ct-isomeric form of {Ru(pap)2} family. The impact of trans or cis orientation of the nitroso group of L/L′ with respect to the N═N (azo) function of pap in the complexes was reflected in the relative lengthening or shortening of the latter distance, respectively. The redox-sensitive bond parameters of 1+ and 3+ reveal the intermediate radical form of L•–, while 2+ involves in situ generated L′–. The multiple redox processes of the complexes in CH3CN are analyzed via experimental and density functional theory (DFT) and time-dependent DFT calculations. One-electron oxidation of the electron paramagnetic resonance-active radical species (1+ and 3+) leads to [RuII(pap)2(L)]2+ involving fully oxidized L0 in 12+ and 32+; the same in 2+ results in a radical species [RuII(pap)2(L′•)]2+ (22+). Successive reductions in each case are either associated with pap or L/L′–-based orbitals, revealing a competitive scenario relating to their π-accepting features. The isolated or electrochemically generated radical species either by oxidation or reduction exhibits near-IR transitions in each case, attributing diverse electronic structures of the complexes in accessible redox states." @default.
• W2560204602 created "2016-12-16" @default.
• W2560204602 creator A5062826786 @default.
• W2560204602 creator A5064625053 @default.
• W2560204602 creator A5083136133 @default.
• W2560204602 date "2016-12-06" @default.
• W2560204602 modified "2023-09-25" @default.
• W2560204602 title "Ruthenium Derivatives of in Situ Generated Redox-Active 1,2-Dinitrosobenzene and 2-Nitrosoanilido. Diverse Structural and Electronic Forms" @default.
• W2560204602 cites W1098958293 @default.
• W2560204602 cites W1602932472 @default.
• W2560204602 cites W1838264503 @default.
• W2560204602 cites W1964675518 @default.
• W2560204602 cites W1967238575 @default.
• W2560204602 cites W1967798471 @default.
• W2560204602 cites W1969360633 @default.
• W2560204602 cites W1970225878 @default.
• W2560204602 cites W1970326168 @default.
• W2560204602 cites W1978303107 @default.
• W2560204602 cites W1978528808 @default.
• W2560204602 cites W1981368803 @default.
• W2560204602 cites W1985250921 @default.
• W2560204602 cites W1987141277 @default.
• W2560204602 cites W1987545190 @default.
• W2560204602 cites W1990376738 @default.
• W2560204602 cites W1996633955 @default.
• W2560204602 cites W1996703366 @default.
• W2560204602 cites W2001465174 @default.
• W2560204602 cites W2004824042 @default.
• W2560204602 cites W2005146343 @default.
• W2560204602 cites W2005562487 @default.
• W2560204602 cites W2006345722 @default.
• W2560204602 cites W2009046603 @default.
• W2560204602 cites W2009578426 @default.
• W2560204602 cites W2015723183 @default.
• W2560204602 cites W2016292274 @default.
• W2560204602 cites W2019459605 @default.
• W2560204602 cites W2021616354 @default.
• W2560204602 cites W2023271753 @default.
• W2560204602 cites W2023275162 @default.
• W2560204602 cites W2024812092 @default.
• W2560204602 cites W2027056314 @default.
• W2560204602 cites W2027063055 @default.
• W2560204602 cites W2028359120 @default.
• W2560204602 cites W2030175511 @default.
• W2560204602 cites W2031212235 @default.
• W2560204602 cites W2033862487 @default.
• W2560204602 cites W2034609199 @default.
• W2560204602 cites W2034904495 @default.
• W2560204602 cites W2037210237 @default.
• W2560204602 cites W2039294840 @default.
• W2560204602 cites W2039501060 @default.
• W2560204602 cites W2039559098 @default.
• W2560204602 cites W2041708768 @default.
• W2560204602 cites W2048158093 @default.
• W2560204602 cites W2050097609 @default.
• W2560204602 cites W2053222012 @default.
• W2560204602 cites W2058848030 @default.
• W2560204602 cites W2059327325 @default.
• W2560204602 cites W2061561689 @default.
• W2560204602 cites W2063663126 @default.
• W2560204602 cites W2068228867 @default.
• W2560204602 cites W2069197437 @default.
• W2560204602 cites W2071073361 @default.
• W2560204602 cites W2071841742 @default.
• W2560204602 cites W2072285153 @default.
• W2560204602 cites W2075064996 @default.
• W2560204602 cites W2076940601 @default.
• W2560204602 cites W2078109230 @default.
• W2560204602 cites W2084469503 @default.
• W2560204602 cites W2084687596 @default.
• W2560204602 cites W2086579657 @default.
• W2560204602 cites W2088791877 @default.
• W2560204602 cites W2091305743 @default.
• W2560204602 cites W2095582621 @default.
• W2560204602 cites W2097060287 @default.
• W2560204602 cites W2098399286 @default.
• W2560204602 cites W2099638906 @default.
• W2560204602 cites W2103029770 @default.
• W2560204602 cites W2107055594 @default.
• W2560204602 cites W2121241715 @default.
• W2560204602 cites W2122078186 @default.
• W2560204602 cites W2128609097 @default.
• W2560204602 cites W2131350133 @default.
• W2560204602 cites W2133228455 @default.
• W2560204602 cites W2138441378 @default.
• W2560204602 cites W2139153094 @default.
• W2560204602 cites W2142494819 @default.
• W2560204602 cites W2149623564 @default.
• W2560204602 cites W2150944722 @default.
• W2560204602 cites W2152781103 @default.
• W2560204602 cites W2156559502 @default.
• W2560204602 cites W2167299542 @default.
• W2560204602 cites W2167935423 @default.
• W2560204602 cites W2169489156 @default.
• W2560204602 cites W2210791076 @default.
• W2560204602 cites W2256403517 @default.
• W2560204602 cites W2291026398 @default.
• W2560204602 cites W2312446970 @default.

• next