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• W2560284498 endingPage "6475" @default.
• W2560284498 startingPage "6472" @default.
• W2560284498 abstract "An electron-deficient amide is utilized as a directing group to functionalize nonactivated C(sp3)–H bonds through radical 1,5-hydrogen abstraction. The γ-bromoamides formed are subsequently converted to γ-lactones under mild conditions. The method described is not limited to tertiary and secondary positions but also allows functionalization of primary nonactivated sp3-hybridized positions in a one-pot sequence. In addition, the broad functional group tolerance renders this method suitable for the late-stage introduction of γ-lactones into complex carbon frameworks." @default.
• W2560284498 created "2016-12-16" @default.
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• W2560284498 date "2016-12-05" @default.
• W2560284498 modified "2023-10-10" @default.
• W2560284498 title "Synthesis of Lactones via C–H Functionalization of Nonactivated C(sp³)–H Bonds" @default.
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• W2560284498 doi "https://doi.org/10.1021/acs.orglett.6b03371" @default.
• W2560284498 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27978701" @default.
• W2560284498 hasPublicationYear "2016" @default.
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